Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis(N-heterocyclic thione) (SCS-NHT) Pd pincer complex

2015 ◽  
Vol 44 (32) ◽  
pp. 14475-14482 ◽  
Author(s):  
Ginger E. Tyson ◽  
Kenan Tokmic ◽  
Casey S. Oian ◽  
Daniel Rabinovich ◽  
Henry U. Valle ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Photophysical Properties ◽  
Pincer Ligand ◽  
Pincer Complex

The first SCS-NHT pincer ligand and its Pd complex.

scholarly journals Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex

2016 ◽  
Vol 7 (4) ◽  
pp. 2579-2586 ◽  
Author(s):  
David Bézier ◽  
Changjian Guan ◽  
Karsten Krogh-Jespersen ◽  
Alan S. Goldman ◽  
Maurice Brookhart
Keyword(s):  
Computational Study ◽  
Rhodium Complex ◽  
Pincer Ligand ◽  
Alkane Dehydrogenation ◽  
Pincer Complex

A rhodium complex based on the bis-phosphine carbazolide pincer ligand was investigated in the context of alkane dehydrogenation and in comparison with its iridium analogue.

Nickel-Catalyzed Direct Alkylation of Terminal Alkynes at Room Temperature: A Hemilabile Pincer Ligand Enhances Catalytic Activity

ACS Catalysis ◽  
2015 ◽  
Vol 5 (2) ◽  
pp. 1164-1171 ◽  
Author(s):  
Pablo M. Pérez García ◽  
Peng Ren ◽  
Rosario Scopelliti ◽  
Xile Hu
Keyword(s):  
Catalytic Activity ◽  
Room Temperature ◽  
Terminal Alkynes ◽  
Pincer Ligand

Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS′-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides

2011 ◽  
Vol 40 (7) ◽  
pp. 1535 ◽  
Author(s):  
D. V. Aleksanyan ◽  
V. A. Kozlov ◽  
Y. V. Nelyubina ◽  
K. A. Lyssenko ◽  
L. N. Puntus ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Benzoic Acid ◽  
Photophysical Properties ◽  
Pincer Complexes

Crystalline Cu(ii) metal–organic frameworks based on a carboxamide pincer ligand and an NCONCON–Pd(ii) pincer complex

CrystEngComm ◽  
2021 ◽  
Author(s):  
Siphelele S. P. Malaza ◽  
Gift Mehlana ◽  
Ocean Cheung ◽  
Roger Hunter ◽  
Banothile C. E. Makhubela
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Organometallic Complexes ◽  
Carbon Dioxide Conversion ◽  
Pincer Ligand ◽  
Pincer Complex ◽  
Metal Organic

Two copper MOFs based on carboxamide linkers are presented. This work shows how organometallic complexes with carboxylate functionalities can be repurposed to produce crystalline MOFs which can be used in carbon dioxide conversion.

scholarly journals Metal–ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand

2016 ◽  
Vol 45 (40) ◽  
pp. 16033-16039 ◽  
Author(s):  
Linda E. Eijsink ◽  
Sébastien C. P. Perdriau ◽  
Johannes G. de Vries ◽  
Edwin Otten
Keyword(s):  
Ruthenium Complex ◽  
Pincer Ligand ◽  
Pincer Complex ◽  
Cooperative Activation ◽  
Metal Ligand

Metal–ligand cooperative activation of nitriles by a de-aromatized Ru pincer complex leads to equilibrium mixtures (tautomers) as a result of ligand deprotonation by the Brønsted basic Ru-ketimido moiety.

Synthesis, structures, photophysical and catalytic properties of benzothienyl iridium(III) complexes

2017 ◽  
Vol 41 (5) ◽  
pp. 287-290 ◽  
Author(s):  
Si-Pei Ye ◽  
Yi-Bi Xie ◽  
Ke-Yan Zhao ◽  
Yang Liu ◽  
Jian Yang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Catalytic Properties ◽  
Photophysical Properties ◽  
Thermally Stable ◽  
X Ray ◽  
X Ray Crystallography ◽  
Borrowing Hydrogen

Bisbenzothienyl iridium(III) complexes, [Ir(bt)2(PR3)]X (bt: 2-phenylbenzo[ d]thiazole, R = n-Bu or Ph, X = OTf, BF4 or SbF6) are reported, two of which, (R = n-Bu or Ph, X = OTf), have been characterised by X-ray crystallography. The complexes are thermally stable and their photophysical properties are presented, together with their catalytic activity in the “borrowing hydrogen reaction” of alcohols with amines.

Improved synthesis of pincer ligand precursor, and synthesis and structural characterization of terphenyl scaffolded S–C–S palladium pincer complex

2009 ◽  
Vol 12 (12) ◽  
pp. 1171-1174 ◽  
Author(s):  
Paul M. Schroder ◽  
Thomas F. Spilker ◽  
Wilson Luu ◽  
James B. Updegraff ◽  
Man Lung Kwan ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Pincer Ligand ◽  
Pincer Complex

Reactivity of a T-Shaped Cobalt(I) Pincer-Complex

2021 ◽  
Author(s):  
Clemens Blasius ◽  
Regina Matveeva ◽  
Hubert Wadepohl ◽  
Lutz H Gade
Keyword(s):  
Carbon Monoxide ◽  
Neutral Ligand ◽  
Pincer Ligand ◽  
Pincer Complex

The reactivity of a paramagnetic T-shaped cobalt(I) complex, [(iPrboxmi)Co], stabilised by a monoanionic bis(oxazolinylmethylidene)-isoindolate (boxmi) NNN pincer ligand is described. The exposure to carbon monoxide as additional neutral ligand resulted...

scholarly journals Pincer-CNC mononuclear, dinuclear and heterodinuclear Au(iii) and Pt(ii) complexes supported by mono- and poly-N-heterocyclic carbenes: synthesis and photophysical properties

2016 ◽  
Vol 45 (13) ◽  
pp. 5549-5556 ◽  
Author(s):  
S. Gonell ◽  
M. Poyatos ◽  
E. Peris
Keyword(s):  
Photophysical Properties ◽  
Heterocyclic Carbenes ◽  
Pincer Ligand

The photophysical properties of a family of cyclometallated Au(iii) and Pt(ii) complexes containing a CNC-pincer ligand supported by pyrene-based mono- or bis-NHC ligands are described, and compared with those shown by related dimetallic complexes of Pt/Au and Ru2.

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