scholarly journals Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid

2015 ◽  
Vol 6 (6) ◽  
pp. 3624-3632 ◽  
Author(s):  
Junying Chen ◽  
Heejung Yoon ◽  
Yong-Min Lee ◽  
Mi Sook Seo ◽  
Ritimukta Sarangi ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Triflic Acid ◽  
Oxygen Atom Transfer ◽  
Oxo Complexes ◽  
Atom Transfer Reactions

Binding of two HOTf molecules to MnIV(O) species resulted in contrasting effects on the reactivities in oxygen atom transfer and H-atom transfer reactions.

Nonheme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and Their Hydrogen-Atom and Oxygen-Atom Transfer Reactions

2015 ◽  
Vol 54 (15) ◽  
pp. 7152-7164 ◽  
Author(s):  
Mainak Mitra ◽  
Hassan Nimir ◽  
Serhiy Demeshko ◽  
Satish S. Bhat ◽  
Sergey O. Malinkin ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Oxygen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxo Complexes ◽  
Pentadentate Ligands ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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