The Metal or the Ligand? The Preferred Locus for Redox Changes in Oxygen Atom Transfer Reactions of Rhenium Amidodiphenoxides

2017 ◽  
Vol 139 (12) ◽  
pp. 4521-4531 ◽  
Author(s):  
Justin M. Hoffman ◽  
Allen G. Oliver ◽  
Seth N. Brown
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


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