A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(vi) complex under electrospray ionisation mass spectrometric conditions

2004 ◽  
pp. 1928 ◽  
Author(s):  
Victor N. Nemykin ◽  
Partha Basu
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


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