The new dicyanoruthenium(iii) building block with 2′-hydroxyacetophenone imine for heterobimetallic complexes

RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 93470-93479 ◽  
Author(s):  
Jing Ru ◽  
Tian-Xiang Zong ◽  
Jing-Yuan Ge ◽  
Min-Xia Yao ◽  
Jing-Lin Zuo
Keyword(s):  
Building Block ◽  
One Dimensional ◽  
Heterobimetallic Complexes ◽  
Magnetostructural Correlation

Five one-dimensional heterobimetallic chains based on the new dicyanoruthenium(iii) complex, trans-(Ph4P)[Ru(L)2(CN)2] (L = 2′-hydroxyacetophenone imine), are synthesized and structurally characterized. Magnetostructural correlation for these compounds is discussed.

Synthesis of One-Dimensional Schiff Base Polymers that Contain an Oligothiophene Building Block on the Graphite Surface

2015 ◽  
Vol 21 (18) ◽  
pp. 6898-6905 ◽  
Author(s):  
Xiu-Ling Sun ◽  
Li-Xia Fan ◽  
Yong-Jing Yang ◽  
Zongxia Guo ◽  
Wei Quan Tian ◽  
...  
Keyword(s):  
Schiff Base ◽  
Building Block ◽  
Graphite Surface ◽  
One Dimensional ◽  
Schiff Base Polymers

One-dimensional cyanide-bridged Fe(III)–Mn(II) magnetic complexes with different configurations derived from a new pentacyanoiron(III) building block

2020 ◽  
Vol 45 (6) ◽  
pp. 373-380
Author(s):  
Xiaoyun Hao ◽  
Yong Dou ◽  
Tong Cao ◽  
Lan Qin ◽  
Zhen Zhou ◽  
...  
Keyword(s):  
Building Block ◽  
One Dimensional

scholarly journals Self-Organization of -Crown Ether Derivatives into Double-Columnar Arrays Controlled by Supramolecular Isomers of Hydrogen-Bonded Anionic Biimidazolate Ni Complexes

2012 ◽  
Vol 2012 ◽  
pp. 1-10
Author(s):  
Makoto Tadokoro ◽  
Kyosuke Isoda ◽  
Yasuko Tanaka ◽  
Yuko Kaneko ◽  
Syoko Yamamoto ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Crown Ether ◽  
Building Block ◽  
The Other ◽  
Optical Isomer ◽  
Self Organization ◽  
Optical Isomers ◽  
One Dimensional ◽  
Molecular Building Block ◽  
Hydrogen Bonded

Anionic tris (biimidazolate) nickelate (II) ([Ni(Hbim)3]−), which is a hydrogen-bonding (H-bonding) molecular building block, undergoes self-organization into honeycomb-sheet superstructures connected by complementary intermolecular H-bonds. The crystal obtained from the stacking of these sheets is assembled into channel frameworks, approximately 2 nm wide, that clathrate two cationic K+-crown ether derivatives organised into one-dimensional (1D) double-columnar arrays. In this study, we have shown that all five cationic guest-included crystals form nanochannel structures that clathrate the 1-D double-columnar arrays of one of the four types of K+-crown ether derivatives, one of which induces a polymorph. This is accomplished by adaptably fitting two types of anionic [Ni(Hbim)3]−host arrays. One is a network with H-bonded linkages alternating between the two different optical isomers of the and types with flexible H-bonded [Ni(Hbim)3]−. The other is a network of a racemate with 1-D H-bonded arrays of the same optical isomer for each type. Thus, [Ni(Hbim)3]−can assemble large cations such as K+crown-ether derivatives into double-columnar arrays by highly recognizing flexible H-bonding arrangements with two host networks of and .

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

2019 ◽  
Vol 55 (86) ◽  
pp. 12992-12995 ◽  
Author(s):  
Zhao-Rui Wen ◽  
Zong-Jie Guan ◽  
Ying Zhang ◽  
Yu-Mei Lin ◽  
Quan-Ming Wang
Keyword(s):  
Building Block ◽  
Linear Chain ◽  
One Dimensional ◽  
Covalently Linked ◽  
Silver Atoms

A unique nanocluster polymer consists of the building block of Au7Ag8 clusters joined together to form a one-dimensional linear chain.

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