[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

2019 ◽  
Vol 55 (86) ◽  
pp. 12992-12995 ◽  
Author(s):  
Zhao-Rui Wen ◽  
Zong-Jie Guan ◽  
Ying Zhang ◽  
Yu-Mei Lin ◽  
Quan-Ming Wang
Keyword(s):  
Building Block ◽  
Linear Chain ◽  
One Dimensional ◽  
Covalently Linked ◽  
Silver Atoms

A unique nanocluster polymer consists of the building block of Au7Ag8 clusters joined together to form a one-dimensional linear chain.

A one-dimensional chloride-bridged PtII/PtIVmixed-valence complex with a 4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate counter-ion

2015 ◽  
Vol 71 (12) ◽  
pp. 1033-1036 ◽  
Author(s):  
Nobuyuki Matsushita ◽  
Ayako Taira
Keyword(s):  
Valence State ◽  
Title Compound ◽  
Linear Chain ◽  
Mixed Valence ◽  
Chain Structure ◽  
Structural Parameter ◽  
One Dimensional ◽  
Square Planar ◽  
Cl Atoms ◽  
Linear Chain Structure

The title compound,catena-poly[[[bis(ethylenediamine-κ2N,N′)platinum(II)]- μ-chlorido-[bis(ethylenediamine)platinum(IV)]-μ-chlorido] tetrakis{4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate} dihydrate], {[PtIIPtIVCl2(C2H8N2)4](HOC6H4N=NC6H4SO3)4·2H2O}n, has a linear chain structure composed of square-planar [Pt(en)2]2+(en is ethylenediamine) and elongated octahedraltrans-[PtCl2(en)2]2+cations stacked alternately, bridged by Cl atoms, along thebaxis. The Pt atoms are located on an inversion centre, while the Cl atoms are disordered over two sites and form a zigzag ...Cl—PtIV—Cl...PtII... chain, with a PtIV—Cl bond length of 2.3140 (14) Å, an interatomic PtII...Cl distance of 3.5969 (15) Å and a PtIV—Cl...PtIIangle of 170.66 (6)°. The structural parameter indicating the mixed-valence state of the Pt atom, expressed by δ = (PtIV—Cl)/(PtII...Cl), is 0.643.

One-dimensional magnetism of a linear chain compound containing yttrium(III) and a nitronyl nitroxide radical

1989 ◽  
Vol 28 (16) ◽  
pp. 3230-3234 ◽  
Author(s):  
Cristiano Benelli ◽  
Andrea Caneschi ◽  
Dante Gatteschi ◽  
Luca Pardi ◽  
Paul Rey
Keyword(s):  
Linear Chain ◽  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Nitronyl Nitroxide Radical ◽  
One Dimensional ◽  
Chain Compound

Synthesis of One-Dimensional Schiff Base Polymers that Contain an Oligothiophene Building Block on the Graphite Surface

2015 ◽  
Vol 21 (18) ◽  
pp. 6898-6905 ◽  
Author(s):  
Xiu-Ling Sun ◽  
Li-Xia Fan ◽  
Yong-Jing Yang ◽  
Zongxia Guo ◽  
Wei Quan Tian ◽  
...  
Keyword(s):  
Schiff Base ◽  
Building Block ◽  
Graphite Surface ◽  
One Dimensional ◽  
Schiff Base Polymers

A 16-connected three-dimensional hydrogen-bonding network in tetrakis(4-aminopyridinium) perylene-3,4,9,10-tetracarboxylate octahydrate

2014 ◽  
Vol 70 (7) ◽  
pp. 668-671 ◽  
Author(s):  
Zhi-Hui Zhang ◽  
Jin-Long Wang ◽  
Ning Gao ◽  
Ming-Yang He
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Linear Chain ◽  
Three Dimensional ◽  
Organic Salt ◽  
Water Molecules ◽  
The Novel ◽  
One Dimensional ◽  
Connected Node ◽  
Hydrogen Bonding Network

The novel title organic salt, 4C5H7N2+·C24H8O84−·8H2O, was obtained from the reaction of perylene-3,4,9,10-tetracarboxylic acid (H4ptca) with 4-aminopyridine (4-ap). The asymmetric unit contains half a perylene-3,4,9,10-tetracarboxylate (ptca4−) anion with twofold symmetry, two 4-aminopyridinium (4-Hap+) cations and four water molecules. Strong N—H...O hydrogen bonds connect each ptca4−anion with four 4-Hap+cations to form a one-dimensional linear chain along the [010] direction, decorated by additional 4-Hap+cations attached by weak N—H...O hydrogen bonds to the ptca4−anions. Intermolecular O—H...O interactions of water molecules with ptca4−and 4-Hap+ions complete the three-dimensional hydrogen-bonding network. From the viewpoint of topology, each ptca4−anion acts as a 16-connected node by hydrogen bonding to six 4-Hap+cations and ten water molecules to yield a highly connected hydrogen-bonding framework. π–π interactions between 4-Hap+cations, and between 4-Hap+cations and ptca4−anions, further stabilize the three-dimensional hydrogen-bonding network.

Electronic and Resonance Raman Spectra of Some New Mixed-Valence Compounds of Pt and Pd with a Metal-Halide Chain

1980 ◽  
Vol 35 (6) ◽  
pp. 676-679 ◽  
Author(s):  
G. C. Papavassiliou ◽  
D. Layek
Keyword(s):  
Raman Spectra ◽  
Linear Chain ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Chain Structure ◽  
One Dimensional ◽  
Resonance Raman Spectra ◽  
The One ◽  
Mixed Valence Compounds ◽  
Linear Chain Structure

Abstract The electronic and resonance Raman spectra of new mixed-valence compounds of the type M2ʹ[M(L)X3][M(L)X5], where Mʹ = K, NH4, M = Pt or Pd, L = NH3 or pyridine, and X = Cl, Br or I, have been studied. The single-crystal polarized reflectance spectra indicate the one-dimensional semiconductor behaviour. The polarized resonance Raman spectra confirm the --M(II)--X-M(IV)-X linear chain structure, which is in accordance with the X-ray results. The polarization of M-N bands can be explained by the Snyder's theory (1971).

One-dimensional cyanide-bridged Fe(III)–Mn(II) magnetic complexes with different configurations derived from a new pentacyanoiron(III) building block

2020 ◽  
Vol 45 (6) ◽  
pp. 373-380
Author(s):  
Xiaoyun Hao ◽  
Yong Dou ◽  
Tong Cao ◽  
Lan Qin ◽  
Zhen Zhou ◽  
...  
Keyword(s):  
Building Block ◽  
One Dimensional

scholarly journals Self-Organization of -Crown Ether Derivatives into Double-Columnar Arrays Controlled by Supramolecular Isomers of Hydrogen-Bonded Anionic Biimidazolate Ni Complexes

2012 ◽  
Vol 2012 ◽  
pp. 1-10
Author(s):  
Makoto Tadokoro ◽  
Kyosuke Isoda ◽  
Yasuko Tanaka ◽  
Yuko Kaneko ◽  
Syoko Yamamoto ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Crown Ether ◽  
Building Block ◽  
The Other ◽  
Optical Isomer ◽  
Self Organization ◽  
Optical Isomers ◽  
One Dimensional ◽  
Molecular Building Block ◽  
Hydrogen Bonded

Anionic tris (biimidazolate) nickelate (II) ([Ni(Hbim)3]−), which is a hydrogen-bonding (H-bonding) molecular building block, undergoes self-organization into honeycomb-sheet superstructures connected by complementary intermolecular H-bonds. The crystal obtained from the stacking of these sheets is assembled into channel frameworks, approximately 2 nm wide, that clathrate two cationic K+-crown ether derivatives organised into one-dimensional (1D) double-columnar arrays. In this study, we have shown that all five cationic guest-included crystals form nanochannel structures that clathrate the 1-D double-columnar arrays of one of the four types of K+-crown ether derivatives, one of which induces a polymorph. This is accomplished by adaptably fitting two types of anionic [Ni(Hbim)3]−host arrays. One is a network with H-bonded linkages alternating between the two different optical isomers of the and types with flexible H-bonded [Ni(Hbim)3]−. The other is a network of a racemate with 1-D H-bonded arrays of the same optical isomer for each type. Thus, [Ni(Hbim)3]−can assemble large cations such as K+crown-ether derivatives into double-columnar arrays by highly recognizing flexible H-bonding arrangements with two host networks of and .

Two cadmium(II) fluorous coordination compounds tuned by different bipyridines

2017 ◽  
Vol 73 (5) ◽  
pp. 424-429 ◽  
Author(s):  
Ya-Jie Kong ◽  
Peng Li ◽  
Li-Juan Han ◽  
Lu-Tong Fan ◽  
Peng-Peng Li ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Coordination Compounds ◽  
Linear Chain ◽  
Three Dimensional ◽  
Chain Structure ◽  
Water Molecules ◽  
Hydrogen Bond Acceptor ◽  
Small Surface ◽  
One Dimensional ◽  
Coordinated Water

Fluorine is the most electronegative element and can be used as an excellent hydrogen-bond acceptor. Fluorous coordination compounds exhibit several advantageous properties, such as enhanced high thermal and oxidative stability, low polarity, weak intermolecular interactions and a small surface tension compared to hydrocarbons. C—H...F—C interactions, although weak, play a significant role in regulating the arrangement of the organic molecules in the crystalline state and stabilizing the secondary structure. Two cadmium(II) fluorous coordination compounds formed from 2,2′-bipyridine, 4,4′-bipyridine and pentafluorobenzoate ligands, namely catena-poly[[aqua(2,2′-bipyridine-κ2 N,N′)(2,3,4,5,6-pentafluorobenzoato-κO)cadmium(II)]-μ-2,3,4,5,6-pentafluorobenzoato-κ2 O:O′], [Cd(C7F5O2)2(C10H8N2)(H2O)] n , (1), and catena-poly[[diaquabis(2,3,4,5,6-pentafluorobenzoato-κO)cadmium(II)]-μ-4,4′-bipyridine-κ2 N:N′], [Cd(C7F5O2)2(C10H8N2)(H2O)2] n , (2), have been synthesized solvothermally and structurally characterized. Compound (1) shows a one-dimensional chain structure composed of Cd—O coordination bonds and is stabilized by π–π stacking and O—H...O hydrogen-bond interactions. Compound (2) displays a one-dimensional linear chain structure formed by Cd—N coordination interactions involving the 4,4′-bipyridine ligand. Adjacent one-dimensional chains are extended into two-dimensional sheets by O—H...O hydrogen bonds between the coordinated water molecules and adjacent carboxylate groups. Moreover, the chains are further linked by C—H...F—C interactions to afford a three-dimensional network. In both structures, hydrogen bonding involving the coordinated water molecules is a primary driving force in the formation of the supramolecular structures.

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