scholarly journals A family of unsymmetrical hydroxyl-substituted BEDT-TTF donors: syntheses, structures and preliminary thin film studies

RSC Advances ◽  
2015 ◽  
Vol 5 (50) ◽  
pp. 40205-40218 ◽  
Author(s):  
Qiang Wang ◽  
Matteo Zecchini ◽  
John D. Wallis ◽  
Yiliang Wu ◽  
Jeremy M. Rawson ◽  
...  

Synthetic routes to three novel OH-functionalized BEDT-TTF donorsH1–H3are presented. Charge transfer salts ofH1and2and polystyrene blend thin films ofH3have been studied after doping with iodine.

2019 ◽  
Vol 52 (2) ◽  
pp. 247-251
Author(s):  
Detlef-M. Smilgies

Recently, surface and thin-film studies using area detectors have become prevalent. An important class of such systems are lamellar thin films formed by small molecules, liquid crystals or semicrystalline polymers. Frequently, the lamellae align more or less parallel to the substrate. Such structures can be easily discerned by their characteristic X-ray scattering close to the incident plane. This paper describes how such patterns can be simulated, in order to extract morphological information about the thin film.


1995 ◽  
Vol 39 ◽  
pp. 659-664 ◽  
Author(s):  
Kenji Ishida ◽  
Akinori Kita ◽  
Kouichi Hayashi ◽  
Toshihisa Horiuchi ◽  
Shoichi Kal ◽  
...  

Thin film technology is rapidly evolving today, and the characterization of the thin film and its surface have become very important issue not only from scientific but also technological viewpoints. Although x-ray diffraction measurements have been used as suitable evaluation methods in crystallography studies, its application to the structural evaluation of the thin films, especially organic one having the low electron densities, is not easy due to the small amounts of scattering volume and the high obstructive scattering noise from the substrate. However, the x-ray diffraction measurements under grazing incidence will aid not only in overcoming the such problems but also in analyzing in-plane structure of the thin films. Therefore, so-called grazing incidence x-ray diffraction (GIXD) has been recognized as one of the most powerful tools for the surface and thin film studies.


2020 ◽  
Vol 2 (11) ◽  
pp. 5171-5180
Author(s):  
Tyler H. Bennett ◽  
Ravi Pamu ◽  
Guang Yang ◽  
Dibyendu Mukherjee ◽  
Bamin Khomami

The photosynthetic protein complex Photosystem I has been incorporated into the metal organic framework ZIF-8 and then reacted with TCNQ to form a conductive charge transfer salt, generating significant photocurrent from a biohybrid photoactive film.


RSC Advances ◽  
2015 ◽  
Vol 5 (7) ◽  
pp. 5231-5236 ◽  
Author(s):  
Peng Wang ◽  
Xiaoming Wen ◽  
Rose Amal ◽  
Yun Hau Ng

Photoactivity and stability of Cu2O–CuO heterojunction thin films are enhanced by incorporating an interlayer of TiO2. The thin TiO2 layer minimises the redox reactions at Cu2O–electrolyte interface and facilitates charge transfer from Cu2O to CuO.


2013 ◽  
Vol 22 ◽  
pp. 576-582 ◽  
Author(s):  
M. C. RAO ◽  
M. S. SHEKHAWAT

Thin film materials are the key elements of continued technological advances made in the fields of optoelectronic, photonic and magnetic devices. Thin film studies have directly or indirectly advanced many new areas of research in solid state physics and chemistry which are based on phenomena uniquely characteristic of the thickness, geometry and structure of the film. The processing of materials into thin films allows easy integration into various types of devices. Thin films are extremely thermally stable and reasonably hard, but they are fragile. On the other hand organic materials have reasonable thermal stability and are tough, but are soft. Thin film mechanical properties can be measured by tensile testing of freestanding films and by the micro beam cantilever deflection technique, but the easiest way is by means of nanoindentation. Optical experiments provide a good way of examining the properties of semiconductors. Particularly measuring the absorption coefficient for various energies gives information about the band gaps of the material. Thin film materials have been used in semiconductor devices, wireless communications, telecommunications, integrated circuits, rectifiers, transistors, solar cells, light-emitting diodes, photoconductors and light crystal displays, lithography, micro- electromechanical systems (MEMS) and multifunctional emerging coatings, as well as other emerging cutting technologies.


2003 ◽  
Vol 137 (1-3) ◽  
pp. 1201-1202 ◽  
Author(s):  
H.Hau Wang ◽  
Catherine Y. Han ◽  
Dong-Youn Noh ◽  
Kyong-Soon Shin ◽  
Gerold A. Willing ◽  
...  

2004 ◽  
Vol 28 (1) ◽  
pp. 52-55 ◽  
Author(s):  
Luca Pilia ◽  
Isabelle Malfant ◽  
Dominique de Caro ◽  
François Senocq ◽  
Antoine Zwick ◽  
...  

Author(s):  
R. C. Moretz ◽  
G. G. Hausner ◽  
D. F. Parsons

Use of the electron microscope to examine wet objects is possible due to the small mass thickness of the equilibrium pressure of water vapor at room temperature. Previous attempts to examine hydrated biological objects and water itself used a chamber consisting of two small apertures sealed by two thin films. Extensive work in our laboratory showed that such films have an 80% failure rate when wet. Using the principle of differential pumping of the microscope column, we can use open apertures in place of thin film windows.Fig. 1 shows the modified Siemens la specimen chamber with the connections to the water supply and the auxiliary pumping station. A mechanical pump is connected to the vapor supply via a 100μ aperture to maintain steady-state conditions.


Sign in / Sign up

Export Citation Format

Share Document