BINOL-Al catalysed asymmetric cyclization and amplification: preparation of optically active menthol analogs

Hisanori Itoh; Hironori Maeda; Shinya Yamada; Yoji Hori; Takashi Mino; Masami Sakamoto

doi:10.1039/c5ob00433k

BINOL-Al catalysed asymmetric cyclization and amplification: preparation of optically active menthol analogs

Organic & Biomolecular Chemistry ◽

10.1039/c5ob00433k ◽

2015 ◽

Vol 13 (20) ◽

pp. 5817-5825 ◽

Cited By ~ 2

Author(s):

Hisanori Itoh ◽

Hironori Maeda ◽

Shinya Yamada ◽

Yoji Hori ◽

Takashi Mino ◽

...

Keyword(s):

Optically Active ◽

Ene Reaction ◽

Aluminum Complexes

We report a highly selective asymmetric ring-closing ene reaction catalyzed by chiral aluminum complexes. Asymmetric amplification of this reaction was investigated by varying the ee of the BINOL employed in the catalyst.

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ChemInform Abstract: Diastereoselective Synthesis of Optically Active Pyrrolizidine and Indolizidine Ring Systems Through Intramolecular Ene Reaction.

ChemInform ◽

10.1002/chin.199125250 ◽

2010 ◽

Vol 22 (25) ◽

pp. no-no

Author(s):

S. DIKE ◽

M. MAHALINGAM ◽

A. KUMAR

Keyword(s):

Optically Active ◽

Diastereoselective Synthesis ◽

Ring Systems ◽

Ene Reaction

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Synthesis of Optically Active α-Methyl β-Hydroperoxy Esters by Diastereoselective Singlet Oxygen Ene Reaction and Horseradish Peroxidase Catalyzed Kinetic Resolution

Monatshefte für Chemie - Chemical Monthly ◽

10.1007/s007060070098 ◽

2000 ◽

Vol 131 (6) ◽

pp. 697-705 ◽

Cited By ~ 3

Author(s):

Waldemar Adam ◽

Chantu R. Saha-Möller ◽

Oliver Weichold

Keyword(s):

Horseradish Peroxidase ◽

Singlet Oxygen ◽

Kinetic Resolution ◽

Optically Active ◽

Ene Reaction

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Synthesis of Optically Active a-Methyl ß-Hydroperoxy Esters by Diastereoselective Singlet Oxygen Ene Reaction and Horseradish Peroxidase Catalyzed Kinetic Resolution

Biocatalysis ◽

10.1007/978-3-7091-6310-8_14 ◽

2000 ◽

pp. 171-179

Author(s):

Waldemar Adam ◽

Chantu R. Saha-Möller ◽

Oliver Weichold

Keyword(s):

Horseradish Peroxidase ◽

Singlet Oxygen ◽

Kinetic Resolution ◽

Optically Active ◽

Ene Reaction

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Total synthesis of optically active cotylenol, a fungal metabolite having a leaf growth activity. Intramolecular ene reaction for an eight-membered ring formation

Tetrahedron ◽

10.1016/s0040-4020(96)00059-2 ◽

1996 ◽

Vol 52 (11) ◽

pp. 3921-3932 ◽

Cited By ~ 31

Author(s):

Nobuo Kato ◽

Hiroaki Okamoto ◽

Hitoshi Takeshita

Keyword(s):

Total Synthesis ◽

Leaf Growth ◽

Membered Ring ◽

Optically Active ◽

Ring Formation ◽

Fungal Metabolite ◽

Ene Reaction ◽

Growth Activity

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Diastereoselective synthesis of optically active pyrrolizidine and indolizidine ring systems through intramolecular ene reaction.

Tetrahedron Letters ◽

10.1016/s0040-4039(00)97696-2 ◽

1990 ◽

Vol 31 (32) ◽

pp. 4641-4644 ◽

Cited By ~ 12

Author(s):

Suneel Y. Dike ◽

Murli Mahalingam ◽

Ashok Kumar

Keyword(s):

Optically Active ◽

Diastereoselective Synthesis ◽

Ring Systems ◽

Ene Reaction

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ChemInform Abstract: Optically Active β-Ketoiminato Cationic Cobalt(III) Complexes: Efficient Catalysts for Enantioselective Carbonyl-Ene Reaction of Glyoxal Derivatives.

ChemInform ◽

10.1002/chin.200152024 ◽

2010 ◽

Vol 32 (52) ◽

pp. no-no

Author(s):

Satoko Kezuka ◽

Taketo Ikeno ◽

Tohru Yamada

Keyword(s):

Optically Active ◽

Ene Reaction

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Optically Active β-Ketoiminato Cationic Cobalt(III) Complexes: Efficient Catalysts for Enantioselective Carbonyl-Ene Reaction of Glyoxal Derivatives

Organic Letters ◽

10.1021/ol015980m ◽

2001 ◽

Vol 3 (12) ◽

pp. 1937-1939 ◽

Cited By ~ 50

Author(s):

Satoko Kezuka ◽

Taketo Ikeno ◽

Tohru Yamada

Keyword(s):

Optically Active ◽

Ene Reaction

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Post-polymerization modification of the side chain in optically active polymers by thiol–ene reaction

Polymer Chemistry ◽

10.1039/c6py01946c ◽

2017 ◽

Vol 8 (6) ◽

pp. 985-994 ◽

Cited By ~ 11

Author(s):

Naoya Kanbayashi ◽

Sou Miyamoto ◽

Yuki Ishido ◽

Taka-aki Okamura ◽

Kiyotaka Onitsuka

Keyword(s):

Optically Active ◽

Side Chain ◽

Optically Active Polymers ◽

Ene Reaction

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ChemInform Abstract: Synthesis of Optically Active Bicyclic Lactone Building Blocks Using Catalytic Enantioselective Glyoxylate-ene Reaction.

ChemInform ◽

10.1002/chin.200004120 ◽

2010 ◽

Vol 31 (4) ◽

pp. no-no

Author(s):

Nicholas Gathergood ◽

Karl Anker Joergensen

Keyword(s):

Building Blocks ◽

Optically Active ◽

Ene Reaction ◽

Bicyclic Lactone

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Synthesis of optically active bicyclic lactone building blocks using catalytic enantioselective glyoxylate-ene reaction

Chemical Communications ◽

10.1039/a905637h ◽

1999 ◽

pp. 1869-1870 ◽

Cited By ~ 14

Author(s):

Nicholas Gathergood ◽

Karl Anker Jørgensen

Keyword(s):

Building Blocks ◽

Optically Active ◽

Ene Reaction ◽

Bicyclic Lactone

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