Optically Active β-Ketoiminato Cationic Cobalt(III) Complexes:  Efficient Catalysts for Enantioselective Carbonyl-Ene Reaction of Glyoxal Derivatives

2001 ◽  
Vol 3 (12) ◽  
pp. 1937-1939 ◽  
Author(s):  
Satoko Kezuka ◽  
Taketo Ikeno ◽  
Tohru Yamada
2015 ◽  
Vol 13 (20) ◽  
pp. 5817-5825 ◽  
Author(s):  
Hisanori Itoh ◽  
Hironori Maeda ◽  
Shinya Yamada ◽  
Yoji Hori ◽  
Takashi Mino ◽  
...  

We report a highly selective asymmetric ring-closing ene reaction catalyzed by chiral aluminum complexes. Asymmetric amplification of this reaction was investigated by varying the ee of the BINOL employed in the catalyst.


2017 ◽  
Vol 8 (6) ◽  
pp. 985-994 ◽  
Author(s):  
Naoya Kanbayashi ◽  
Sou Miyamoto ◽  
Yuki Ishido ◽  
Taka-aki Okamura ◽  
Kiyotaka Onitsuka

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