scholarly journals Understanding and optimising the packing density of perylene bisimide layers on CVD-grown graphene

Nanoscale ◽  
2015 ◽  
Vol 7 (39) ◽  
pp. 16337-16342 ◽  
Author(s):  
Nina C. Berner ◽  
Sinéad Winters ◽  
Claudia Backes ◽  
Chanyoung Yim ◽  
Kim C. Dümbgen ◽  
...  

We observe and characterise contamination-related differences in the packing density of wet-chemically deposited perylene bisimide derivatives on CVD graphene.

RSC Advances ◽  
2019 ◽  
Vol 9 (71) ◽  
pp. 41447-41452 ◽  
Author(s):  
Zehao Wu ◽  
Xuewei Zhang ◽  
Atanu Das ◽  
Jinglan Liu ◽  
Zhenxing Zou ◽  
...  

The quality evolution of as-grown graphene during wet transfer from Cu to SiO2/Si substrate is investigated by Raman spectroscopy and the relavant factors during this process are identified.


Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 919
Author(s):  
Sunghun Cho ◽  
Jun Seop Lee ◽  
Hyeji Jang ◽  
Seorin Park ◽  
Ji Hyun An ◽  
...  

In this work, we report a facile way to control crystalline structures of polyketone (PK) films by combining plasma surface treatment with chemical vapor deposition (CVD) technique. The crystalline structure of PKs grown on plasma-treated graphene and the resulting thermal and mechanical properties were systematically discussed. Every graphene sheet used in this work was produced by CVD method and the production of PKs having different crystallinity were performed on the O2- and N2-doped graphene sheets. It was evident that the CVD-grown graphene sheets acted as the nucleating agents for promoting the crystallization of β-form PK, while suppressing the growth of α-form PK crystals. Regardless of the increase in surface roughness of graphene, surface functionality of the CVD-grown graphene was found to be an important factor in determining the crystalline structure of PK. N2 plasma treatment of the CVD-grown graphene promoted growth of the β-form PK, whereas the O2 plasma treatment of CVD graphene led to transformation of the unoriented β-form PK into the oriented α-form PK. Thus, the resulting thermal and mechanical properties of the PKs were highly dependent on the surface functionality of the CVD graphene. The method of controlling crystalline structure of the PKs suggested in this study, is expected to be very effective in realizing the PK with good processability, heat resistance and mechanical properties.


RSC Advances ◽  
2014 ◽  
Vol 4 (46) ◽  
pp. 23952-23956 ◽  
Author(s):  
Adeline Huiling Loo ◽  
Adriano Ambrosi ◽  
Alessandra Bonanni ◽  
Martin Pumera

Herein, we aim to draw attention to employing chemical vapour deposition (CVD) method grown graphene as a potential platform for immunosensing of IgG.


MRS Bulletin ◽  
1997 ◽  
Vol 22 (10) ◽  
pp. 19-27 ◽  
Author(s):  
Wei William Lee ◽  
Paul S. Ho

Continuing improvement of microprocessor performance historically involves a decrease in the device size. This allows greater device speed, an increase in device packing density, and an increase in the number of functions that can reside on a single chip. However higher packing density requires a much larger increase in the number of interconnects. This has led to an increase in the number of wiring levels and a reduction in the wiring pitch (sum of the metal line width and the spacing between the metal lines) to increase the wiring density. The problem with this approach is that—as device dimensions shrink to less than 0.25 μm (transistor gate length)—propagation delay, crosstalk noise, and power dissipation due to resistance-capacitance (RC) coupling become significant due to increased wiring capacitance, especially interline capacitance between the metal lines on the same metal level. The smaller line dimensions increase the resistivity (R) of the metal lines, and the narrower interline spacing increases the capacitance (C) between the lines. Thus although the speed of the device will increase as the feature size decreases, the interconnect delay becomes the major fraction of the total delay and limits improvement in device performance.To address these problems, new materials for use as metal lines and interlayer dielectrics (ILD) as well as alternative architectures have been proposed to replace the current Al(Cu) and SiO2 interconnect technology.


2021 ◽  
Author(s):  
Roberto Li Voti ◽  
Grigore Leahu ◽  
Concita Sibilia ◽  
Roberto Matassa ◽  
Giuseppe Familiari ◽  
...  

Photoacoustic detection signal has been used to build a new strategy to determine the mesoscale self-assembly of metal nanoparticles in terms of size distribution and aggregate packing density (metal nanoparticles...


Author(s):  
Guanghui Ouyang ◽  
David Bialas ◽  
Frank Würthner

Correction for ‘Reversible fluorescence modulation through the photoisomerization of an azobenzene-bridged perylene bisimide cyclophane’ by Guanghui Ouyang et al., Org. Chem. Front., 2021, DOI: 10.1039/D0QO01635G.


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