Recent advances in the transition metal catalyzed carbonylation of alkynes, arenes and aryl halides using CO surrogates

2015 ◽  
Vol 5 (10) ◽  
pp. 4663-4702 ◽  
Author(s):  
Prashant Gautam ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Carbon Monoxide ◽  
Transition Metal ◽  
Organic Synthesis ◽  
Aryl Halides ◽  
Industrial Synthesis ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Important Position

Transition metal catalyzed carbonylation reactions using carbon monoxide as the C-1 source have occupied an all important position in catalysis which is subsequently related to organic synthesis and industrial synthesis of molecules.

Transition-Metal-Catalyzed Intermolecular C–H Carbonylation toward Amides

Synlett ◽  
2020 ◽  
Vol 32 (01) ◽  
pp. 07-13 ◽  
Author(s):  
Ji-Bao Xia ◽  
Yan-Lin Li ◽  
Zheng-Yang Gu
Keyword(s):  
Carbon Monoxide ◽  
Transition Metal ◽  
Organic Azides ◽  
Amide Linkage ◽  
Amide Synthesis ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The amide linkage is one of the most important structural moieties in both chemistry and biology. Here, we briefly discuss recent advances in catalytic intermolecular C–H carbonylation reactions for the synthesis of amides, with particular attention to our intermolecular C–H amidation of arenes with carbon monoxide and organic azides to produce amides.1 Introduction2 Representative Methods for Amide Synthesis3 C–H Aminocarbonylation with Carbon Monoxide and Amines4 C–H Amidation to Amides with Carbon Monoxide and Azides5 Summary and Outlook

Recent advances in Rhodium-catalyzed C(sp2)–H (hetero)arylation

2021 ◽  
Author(s):  
Zixian Yang ◽  
Jin-Tao Yu ◽  
Changduo Pan
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Complex Structures ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Common Behaviour ◽  
Metal Catalyzed

Arylation is a common behaviour in organic synthesis for the construction of complex structures, especially the biaryls. Among those reported arylation procedures, the transition-metal-catalyzed direct C-H arylations were developed rapidly...

Recent Advances in the Synthesis of Acyl Fluorides

Synthesis ◽  
2020 ◽  
Author(s):  
Marie Gonay ◽  
Chloé Batisse ◽  
Jean-François Paquin
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Peptide Synthesis ◽  
Uranium Hexafluoride ◽  
Metal Catalysts ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Nucleophilic Fluorination ◽  
Bromine Trifluoride

AbstractAcyl fluorides are valuable intermediates in organic synthesis. They are increasingly employed in peptide synthesis, in challenging esterification and amidation reactions or in transition-metal-catalyzed transformations. This review summarizes recent advances in their preparation.1 Introduction2 Nucleophilic Fluorination2.1 α-Fluoroamine Reagents2.2 Sulfur-Based Reagents2.3 Metal Catalysts2.4 Phosphorus-Based Reagents2.5 N,N′-Dicyclohexylcarbodiimide/HF·Pyridine2.6 Uranium Hexafluoride2.7 Bromine Trifluoride3 Radical Fluorination4 Conclusion

scholarly journals Recent advances in transition-metal-catalyzed incorporation of fluorine-containing groups

2019 ◽  
Vol 15 ◽  
pp. 2213-2270 ◽  
Author(s):  
Xiaowei Li ◽  
Xiaolin Shi ◽  
Xiangqian Li ◽  
Dayong Shi
Keyword(s):  
Transition Metal ◽  
Physical Properties ◽  
Organic Synthesis ◽  
Organic Molecules ◽  
Powerful Method ◽  
Fluorine Chemistry ◽  
Recent Advances ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Fluorine chemistry plays an increasingly important role in pharmaceutical, agricultural, and materials industries. The incorporation of fluorine-containing groups into organic molecules can improve their chemical and physical properties, which attracts continuous interest in organic synthesis. Among various reported methods, transition-metal-catalyzed fluorination/fluoroalkylation has emerged as a powerful method for the construction of these compounds. This review attempts to describe the major advances in the transition-metal-catalyzed incorporation of fluorine, trifluoromethyl, difluoromethyl, trifluoromethylthio, and trifluoromethoxy groups reported between 2011 and 2019.

Chelation-assisted transition metal-catalysed C–H chalcogenylations

2020 ◽  
Vol 7 (8) ◽  
pp. 1022-1060 ◽  
Author(s):  
Wenbo Ma ◽  
Nikolaos Kaplaneris ◽  
Xinyue Fang ◽  
Linghui Gu ◽  
Ruhuai Mei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Site Selectivity ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.

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