Construction of pillar[6]arene-based CO2 and UV dual-responsive supra-amphiphile and application in controlled self-assembly

2016 ◽  
Vol 52 (15) ◽  
pp. 3211-3214 ◽  
Author(s):  
Jie Yang ◽  
Li Shao ◽  
Guocan Yu

A gas and photo dual-responsive host–guest recognition was established in an aqueous medium. This recognition motif was further applied for the construction of a supra-amphiphile, which reversibly self-assembled into vesicles upon UV/vis irradiation or bubbling with N2/CO2.

2018 ◽  
Vol 54 (19) ◽  
pp. 2432-2435 ◽  
Author(s):  
Gurbir Singh ◽  
Manvir Kaur ◽  
Markus Drechsler ◽  
Tejwant Singh Kang

A first report on bilayer architectures from self-assembly of SAILs without any additive in aqueous solutions at very low concentrations.


RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 30075-30083 ◽  
Author(s):  
Mayte A. Martínez-Aguirre ◽  
Jorge M. del Campo ◽  
Sigfrido Escalante-Tovar ◽  
Anatoly K. Yatsimirsky

A tetraanionic [2 + 2] boronate ester macrocycle is self-assembled in water containing 0–5% vol DMSO and binds efficiently various cationic guests including R4N+ cations, choline, acetylcholine, 1-methylnicotinamide and an alkaloid berberine.


2015 ◽  
Vol 6 (13) ◽  
pp. 2407-2415 ◽  
Author(s):  
Jinming Hu ◽  
Michael R. Whittaker ◽  
Yang Li ◽  
John F. Quinn ◽  
Thomas P. Davis

A nitric oxide (NO) and carbon dioxide (CO2) dual-responsive block copolymer was self-assembled in aqueous solution upon gas stimuli to form nanostructures.


2016 ◽  
Vol 40 (12) ◽  
pp. 9890-9894 ◽  
Author(s):  
Danyu Xia ◽  
Liqing Shangguan ◽  
Min Xue ◽  
Bingbing Shi

A new host–guest system based on a water-soluble pillar[6]arene (WP6) was designed and its application in the construction of dual-responsive self-assembly of a bola-type supra-amphiphile and application in controlled release was achieved.


MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3507-3520
Author(s):  
Chunhui Dai ◽  
Kriti Agarwal ◽  
Jeong-Hyun Cho

AbstractNanoscale self-assembly, as a technique to transform two-dimensional (2D) planar patterns into three-dimensional (3D) nanoscale architectures, has achieved tremendous success in the past decade. However, an assembly process at nanoscale is easily affected by small unavoidable variations in sample conditions and reaction environment, resulting in a low yield. Recently, in-situ monitored self-assembly based on ion and electron irradiation has stood out as a promising candidate to overcome this limitation. The usage of ion and electron beam allows stress generation and real-time observation simultaneously, which significantly enhances the controllability of self-assembly. This enables the realization of various complex 3D nanostructures with a high yield. The additional dimension of the self-assembled 3D nanostructures opens the possibility to explore novel properties that cannot be demonstrated in 2D planar patterns. Here, we present a rapid review on the recent achievements and challenges in nanoscale self-assembly using electron and ion beam techniques, followed by a discussion of the novel optical properties achieved in the self-assembled 3D nanostructures.


2020 ◽  
Author(s):  
Daniel B. Straus ◽  
Robert J. Cava

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies.


2021 ◽  
Vol 11 (7) ◽  
pp. 3254
Author(s):  
Marco Pisco ◽  
Francesco Galeotti

The realization of advanced optical fiber probes demands the integration of materials and structures on optical fibers with micro- and nanoscale definition. Although researchers often choose complex nanofabrication tools to implement their designs, the migration from proof-of-principle devices to mass production lab-on-fiber devices requires the development of sustainable and reliable technology for cost-effective production. To make it possible, continuous efforts are devoted to applying bottom-up nanofabrication based on self-assembly to decorate the optical fiber with highly ordered photonic structures. The main challenges still pertain to “order” attainment and the limited number of implementable geometries. In this review, we try to shed light on the importance of self-assembled ordered patterns for lab-on-fiber technology. After a brief presentation of the light manipulation possibilities concerned with ordered structures, and of the new prospects offered by aperiodically ordered structures, we briefly recall how the bottom-up approach can be applied to create ordered patterns on the optical fiber. Then, we present un-attempted methodologies, which can enlarge the set of achievable structures, and can potentially improve the yielding rate in finely ordered self-assembled optical fiber probes by eliminating undesired defects and increasing the order by post-processing treatments. Finally, we discuss the available tools to quantify the degree of order in the obtained photonic structures, by suggesting the use of key performance figures of merit in order to systematically evaluate to what extent the pattern is really “ordered”. We hope such a collection of articles and discussion herein could inspire new directions and hint at best practices to fully exploit the benefits inherent to self-organization phenomena leading to ordered systems.


2021 ◽  
pp. 2102027
Author(s):  
Da‐xia Zhang ◽  
Jiang Du ◽  
Rui Wang ◽  
Jian Luo ◽  
Tong‐fang Jing ◽  
...  

2009 ◽  
Vol 143 ◽  
pp. 345 ◽  
Author(s):  
Aurelie M. Brizard ◽  
Marc C. A. Stuart ◽  
Jan H. van Esch

2021 ◽  
Author(s):  
Yanfen Jiang ◽  
Shuqi Dong ◽  
Guoyang Qin ◽  
Li Liu ◽  
Hanying Zhao

Alkylation of thioether-containing block copolymer simultaneously incorporated sulfoniums and phenylboronic acid moieties. The co-assembly of this cationic polymer and protein generated micelles with an H2O2-and ATP-responsive release profile.


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