Cu(ii)-catalyzed esterification reaction via aerobic oxidative cleavage of C(CO)–C(alkyl) bonds

2016 ◽  
Vol 52 (10) ◽  
pp. 2145-2148 ◽  
Author(s):  
Ran Ma ◽  
Liang-Nian He ◽  
An-Hua Liu ◽  
Qing-Wen Song
Keyword(s):  
Nucleophilic Addition ◽  
Bond Cleavage ◽  
Oxidative Cleavage ◽  
Esterification Reaction ◽  
Oxidative Esterification

Cu(ii)-catalyzed aerobic oxidative esterification of simple ketones is realized through α-oxygenation/esterification/nucleophilic addition/C–C bond cleavage with the release of CO2.

Catalytic oxidative C–C bond cleavage route of levulinic acid and methyl levulinate

RSC Advances ◽  
2016 ◽  
Vol 6 (76) ◽  
pp. 72744-72749 ◽  
Author(s):  
Fei Xia ◽  
Zhongtian Du ◽  
Junxia Liu ◽  
Yangyang Ma ◽  
Jie Xu
Keyword(s):  
Levulinic Acid ◽  
Bond Cleavage ◽  
Oxidative Cleavage ◽  
Methyl Levulinate ◽  
The Difference

The difference in the catalytic oxidative cleavage route between levulinic acid and methyl levulinate was intensively investigated.

Hydroxyl Radical-Mediated Oxidative Cleavage of C=C Band and Further Esterification Reaction by Heterogeneous Semiconductor Photocatalysis

2021 ◽  
Author(s):  
Hui Wang ◽  
Rui Jia ◽  
Mei Hong ◽  
Hongyan Miao ◽  
Bang-qing Ni ◽  
...  
Keyword(s):  
Hydroxyl Radical ◽  
Carbonyl Compounds ◽  
Carbon Nitride ◽  
Oxidative Cleavage ◽  
Esterification Reaction ◽  
Semiconductor Photocatalysis

A hydroxyl radical-mediated aerobic cleavage of alkenes and further sequence esterification reaction for the preparation of carbonyl compounds has been developed by using tubular carbon nitride (TCN) as a general...

ChemInform Abstract: PIFA-Mediated Esterification Reaction of Alkynes with Alcohols via Oxidative Cleavage of Carbon Triple Bonds.

ChemInform ◽  
2014 ◽  
Vol 45 (36) ◽  
pp. no-no
Author(s):  
Qing Jiang ◽  
An Zhao ◽  
Bin Xu ◽  
Jing Jia ◽  
Xin Liu ◽  
...  
Keyword(s):  
Oxidative Cleavage ◽  
Esterification Reaction ◽  
Triple Bonds

ChemInform Abstract: N-Heterocyclic Carbene-Catalyzed Oxidative Esterification Reaction of Aldehydes with Alkyl Halides under Aerobic Conditions.

ChemInform ◽  
2012 ◽  
Vol 43 (14) ◽  
pp. no-no
Author(s):  
Yang-Chun Xin ◽  
Shi-Hui Shi ◽  
Dong-Dong Xie ◽  
Xin-Ping Hui ◽  
Peng-Fei Xu
Keyword(s):  
Alkyl Halides ◽  
Esterification Reaction ◽  
Aerobic Conditions ◽  
Oxidative Esterification

N-Heterocyclic Carbene-Catalyzed Oxidative Esterification Reaction of Aldehydes with Alkyl Halides under Aerobic Conditions

2011 ◽  
Vol 2011 (32) ◽  
pp. 6527-6531 ◽  
Author(s):  
Yang-Chun Xin ◽  
Shi-Hui Shi ◽  
Dong-Dong Xie ◽  
Xin-Ping Hui ◽  
Peng-Fei Xu
Keyword(s):  
Alkyl Halides ◽  
Esterification Reaction ◽  
Aerobic Conditions ◽  
Oxidative Esterification

Copper-catalyzed aerobic oxidative cleavage of C–C bonds in epoxides leading to aryl nitriles and aryl aldehydes

2015 ◽  
Vol 51 (30) ◽  
pp. 6572-6575 ◽  
Author(s):  
Lijun Gu ◽  
Cheng Jin
Keyword(s):  
Bond Cleavage ◽  
Oxidative Cleavage ◽  
Single Bond ◽  
Aryl Aldehydes ◽  
Aryl Nitriles

Novel copper-catalyzed aerobic synthesis of aryl nitriles and aldehydes from epoxides via C–C single bond cleavage has been discovered.

Asymmetric synthesis of 3-aryl-substituted 2,3-dihydro-1H-isoindol-1-ones

2001 ◽  
Vol 79 (11) ◽  
pp. 1528-1535 ◽  
Author(s):  
Dieter Enders ◽  
Volker Braig ◽  
Gerhard Raabe
Keyword(s):  
Asymmetric Synthesis ◽  
Bond Cleavage ◽  
Oxidative Cleavage ◽  
Ring Closure

The first asymmetric synthesis of 3-aryl substituted 2,3-dihydro-1H-isoindol-1-ones via a tandem nucleophilic 1,2-addition ring closure procedure from SAMP and (or) RAMP hydrazones and subsequent oxidative cleavage of the auxiliary is reported.Key words: isoindolinones, asymmetric synthesis, hydrazones, 1,2-addition, N—N bond cleavage.

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