Copper-catalyzed aerobic oxidative cleavage of C–C bonds in epoxides leading to aryl nitriles and aryl aldehydes

2015 ◽  
Vol 51 (30) ◽  
pp. 6572-6575 ◽  
Author(s):  
Lijun Gu ◽  
Cheng Jin
Keyword(s):  
Bond Cleavage ◽  
Oxidative Cleavage ◽  
Single Bond ◽  
Aryl Aldehydes ◽  
Aryl Nitriles

Novel copper-catalyzed aerobic synthesis of aryl nitriles and aldehydes from epoxides via C–C single bond cleavage has been discovered.

Iron-catalyzed oxidative C–C(vinyl) σ-bond cleavage of allylarenes to aryl aldehydes at room temperature with ambient air

2019 ◽  
Vol 55 (33) ◽  
pp. 4817-4820 ◽  
Author(s):  
Binbin Liu ◽  
Lu Cheng ◽  
Penghui Hu ◽  
Fangning Xu ◽  
Dan Li ◽  
...  
Keyword(s):  
Room Temperature ◽  
Bond Cleavage ◽  
Ambient Air ◽  
Single Bond ◽  
Aryl Aldehydes

The iron-catalyzed C−C single bond cleavage and oxidation of allylarenes without the assistance of heteroatoms/directing groups to produce aryl aldehydes is disclosed.

Catalyst-free photoinduced selective oxidative C(sp3)–C(sp3) bond cleavage in arylamines

2021 ◽  
Author(s):  
Jingwei Zhou ◽  
Songping Wang ◽  
Wentao Duan ◽  
Qi Lian ◽  
Wentao Wei
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Bond Cleavage ◽  
Oxidative Cleavage ◽  
Light Irradiation ◽  
Single Bond ◽  
Catalyst Free ◽  
Site Selective

By introducing a polar atom at the γ-position of amine, the site-selective oxidative cleavage of the saturated C–C single bond in arylamines can be easily achieved by simple visible light irradiation with O2 as a benign oxidant and catalyst free.

Rh(iii)-Catalyzed Csp2–Csp3 bond alkoxylation of α-indolyl alcohols via C–C σ bond cleavage

2021 ◽  
Author(s):  
Can Yang ◽  
Zhipeng Liu ◽  
Xinwei Hu ◽  
Haisheng Xie ◽  
Huanfeng Jiang ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Single Bond ◽  
Sigma Bond

A Rh(iii)-catalyzed direct Csp2–Csp3 bond alkoxylation of α-(2-indolyl)alcohols with alcohols has been achieved via C–C sigma bond/C–O single bond switch.

Catalytic oxidative C–C bond cleavage route of levulinic acid and methyl levulinate

RSC Advances ◽  
2016 ◽  
Vol 6 (76) ◽  
pp. 72744-72749 ◽  
Author(s):  
Fei Xia ◽  
Zhongtian Du ◽  
Junxia Liu ◽  
Yangyang Ma ◽  
Jie Xu
Keyword(s):  
Levulinic Acid ◽  
Bond Cleavage ◽  
Oxidative Cleavage ◽  
Methyl Levulinate ◽  
The Difference

The difference in the catalytic oxidative cleavage route between levulinic acid and methyl levulinate was intensively investigated.

Oxidative Cleavage of α-Aryl Aldehydes Using Iodosylbenzene

2012 ◽  
Vol 14 (19) ◽  
pp. 5078-5081 ◽  
Author(s):  
Nizam Havare ◽  
Dietmar A. Plattner
Keyword(s):  
Oxidative Cleavage ◽  
Aryl Aldehydes

Cu-mediated nitrogen atom transfer via CN bond cleavage

2015 ◽  
Vol 13 (39) ◽  
pp. 9948-9952 ◽  
Author(s):  
Lixin Liu ◽  
Jianyu Dong ◽  
Yaxing Zhang ◽  
Yongbo Zhou ◽  
Shuang-Feng Yin
Keyword(s):  
Nitrogen Atom ◽  
Triple Bond ◽  
Organic Molecules ◽  
Bond Cleavage ◽  
Atom Transfer ◽  
Aryl Nitriles

A nitrogen atom transfer to organic molecules affording aryl nitriles via Cu-mediated C–N triple bond cleavage is firstly developed.

scholarly journals Oxidative skeletal rearrangement of 1,1′-binaphthalene-2,2′-diamines (BINAMs) via C–C bond cleavage and nitrogen migration: a versatile synthesis of U-shaped azaacenes

2014 ◽  
Vol 50 (71) ◽  
pp. 10291-10294 ◽  
Author(s):  
Youhei Takeda ◽  
Masato Okazaki ◽  
Satoshi Minakata
Keyword(s):  
Bond Cleavage ◽  
Single Bond ◽  
Skeletal Rearrangement

An oxidative skeletal rearrangement of 1,1′-binaphthalene-2,2′-diamines (BINAMs) that involves the cleavage of a strong C–C single bond of the binaphthalene unit and the nitrogen migration has been discovered.

scholarly journals Iron Catalyzed C-C Single Bond Cleavage of Alcohols

2021 ◽  
Author(s):  
Wei Liu ◽  
Qiang Wu ◽  
Miao Wang ◽  
Yahao Huang ◽  
Peng Hu
Keyword(s):  
Bond Cleavage ◽  
Single Bond

scholarly journals Iron Catalyzed C-C Single Bond Cleavage of Alcohols

2021 ◽  
Author(s):  
Wei Liu ◽  
Qiang Wu ◽  
Miao Wang ◽  
Yahao Huang ◽  
Peng Hu
Keyword(s):  
Bond Cleavage ◽  
Single Bond
Sign in / Sign up

Export Citation Format

Share Document