ChemInform Abstract: N-Heterocyclic Carbene-Catalyzed Oxidative Esterification Reaction of Aldehydes with Alkyl Halides under Aerobic Conditions.

ChemInform ◽  
2012 ◽  
Vol 43 (14) ◽  
pp. no-no
Author(s):  
Yang-Chun Xin ◽  
Shi-Hui Shi ◽  
Dong-Dong Xie ◽  
Xin-Ping Hui ◽  
Peng-Fei Xu
Keyword(s):  
Alkyl Halides ◽  
Esterification Reaction ◽  
Aerobic Conditions ◽  
Oxidative Esterification

N-Heterocyclic Carbene-Catalyzed Oxidative Esterification Reaction of Aldehydes with Alkyl Halides under Aerobic Conditions

2011 ◽  
Vol 2011 (32) ◽  
pp. 6527-6531 ◽  
Author(s):  
Yang-Chun Xin ◽  
Shi-Hui Shi ◽  
Dong-Dong Xie ◽  
Xin-Ping Hui ◽  
Peng-Fei Xu
Keyword(s):  
Alkyl Halides ◽  
Esterification Reaction ◽  
Aerobic Conditions ◽  
Oxidative Esterification

ChemInform Abstract: Access to Aryl Mellitic Acid Esters Through a Surprising Oxidative Esterification Reaction.

ChemInform ◽  
2014 ◽  
Vol 45 (47) ◽  
pp. no-no
Author(s):  
Margarita R. Geraskina ◽  
Mark J. Juetten ◽  
Arthur H. Winter
Keyword(s):  
Esterification Reaction ◽  
Oxidative Esterification ◽  
Mellitic Acid ◽  
Acid Esters

Access to Aryl Mellitic Acid Esters through a Surprising Oxidative Esterification Reaction

2014 ◽  
Vol 79 (11) ◽  
pp. 5334-5337 ◽  
Author(s):  
Margarita R. Geraskina ◽  
Mark J. Juetten ◽  
Arthur H. Winter
Keyword(s):  
Esterification Reaction ◽  
Oxidative Esterification ◽  
Mellitic Acid ◽  
Acid Esters

scholarly journals Cytosine Palladium Complex Supported on Ordered Mesoporous Silica as Highly Efficient and Reusable Nanocatalyst for One-Pot Oxidative Esterification of Aldehydes

Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1482
Author(s):  
Fatemeh Rajabi ◽  
Chin Hua Chia ◽  
Mika Sillanpää ◽  
Leonid G. Voskressensky ◽  
Rafael Luque
Keyword(s):  
Large Scale ◽  
Esterification Reaction ◽  
Ambient Conditions ◽  
One Pot ◽  
Food Ingredients ◽  
Green Protocol ◽  
Oxidative Esterification ◽  
Mesoporous Organosilica ◽  
Ordered Mesoporous ◽  
High Yields

The synthesis of esters is one of the most fundamental and significant subjects in organic chemistry and chemical industry because they are used in high-value products such as cosmetics, biofuel, pharmaceuticals, surfactants, and food ingredients. In this study, an efficient, economic, sustainable, and green protocol for oxidative esterification reaction has been developed. A one-pot direct transformation of aliphatic, aromatic, and unsaturated aldehydes into esters in the presence of oxygen has been carried out over mesoporous organosilica-supported palladium nanocatalyst (Pd-Cyt@SBA-15) under ambient conditions. Pd-Cyt@SBA-15 efficiently catalyzed selectively large-scale conversion of aldehydes into esters in high yields and large turnover numbers (TON = 98,000). Pd-Cyt@SBA-15 nanocatalyst demonstrated excellent reusability and stability and could be recycled up to ten times without loss of significant reactivity. ICP-AES analysis showed that no leaching of active palladium species occurred during the recycling process of the heterogeneous Pd-Cyt@SBA-15 nanocatalyst.

Highly adequate oxidative esterification of α-carbonyl aldehydes with alkyl halides in TBAI/TBHP mediated system

2019 ◽  
Vol 49 (10) ◽  
pp. 1325-1333
Author(s):  
Pooja L. Bhargude ◽  
Jatin J. Lade ◽  
Bhausaheb N. Patil ◽  
Kamlesh S. Vadagaonkar ◽  
Atul C. Chaskar
Keyword(s):  
Alkyl Halides ◽  
Oxidative Esterification
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