Analysis of charge transport in high-mobility diketopyrrolopyrole polymers by space charge limited current and time of flight methods

RSC Advances ◽  
2014 ◽  
Vol 4 (67) ◽  
pp. 35344 ◽  
Author(s):  
Kwang Hee Cheon ◽  
Jangwhan Cho ◽  
Byung Tack Lim ◽  
Hui-Jun Yun ◽  
Soon-Ki Kwon ◽  
...  
2008 ◽  
Vol 93 (3) ◽  
pp. 033303 ◽  
Author(s):  
Dae Sung Chung ◽  
Dong Hoon Lee ◽  
Chanwoo Yang ◽  
Kipyo Hong ◽  
Chan Eon Park ◽  
...  

2018 ◽  
Vol 9 (4) ◽  
Author(s):  
Jason A. Röhr ◽  
Xingyuan Shi ◽  
Saif A. Haque ◽  
Thomas Kirchartz ◽  
Jenny Nelson

2017 ◽  
Vol 8 ◽  
pp. 1277-1282 ◽  
Author(s):  
Vineeth Kumar Bandari ◽  
Lakshmi Varadharajan ◽  
Longqian Xu ◽  
Abdur Rehman Jalil ◽  
Mirunalini Devarajulu ◽  
...  

The investigation of charge transport in organic nanocrystals is essential to understand nanoscale physical properties of organic systems and the development of novel organic nanodevices. In this work, we fabricate organic nanocrystal diodes contacted by rolled-up robust nanomembranes. The organic nanocrystals consist of vanadyl phthalocyanine and copper hexadecafluorophthalocyanine heterojunctions. The temperature dependent charge transport through organic nanocrystals was investigated to reveal the transport properties of ohmic and space-charge-limited current under different conditions, for instance, temperature and bias.


2015 ◽  
Vol 68 (11) ◽  
pp. 1741 ◽  
Author(s):  
Leanne Murphy ◽  
Bin Sun ◽  
Wei Hong ◽  
Hany Aziz ◽  
Yuning Li

We studied the vertical and lateral charge transport characteristics of a diketopyrrolopyrrole polymer donor (D)–PC61BM acceptor (A) system by measuring the space charge limited current (SCLC) mobility and field-effect mobility respectively. It was found that with an increase in annealing temperature, the SCLC hole mobility decreased for the pure polymer (PDBFBT) but increased for the PDBFBT:PC61BM blends, which could be explained by changes in the crystallinity and crystal orientation (edge-on versus face-on). The pure PDBFBT and most blend films showed the maximum field-effect hole mobility (µh) when annealed at 100°C, which then declined as the annealing temperature was further increased. Surprisingly, the D/A = 1/1 blend films annealed at high temperatures exhibited an abrupt increase in the field-effect µh. This unusual phenomenon was interpreted by the antiplasticization effect of PC61BM, which promoted the molecular organization of the polymer. The effect of annealing on the carrier mobility was further correlated with the performance of inverted organic solar cell devices with the PDBFBT:PC61BM blend (D/A = 1/3). Thermal annealing at high temperatures (>100°C) was found to obstruct electron transport and cause the device performance to significantly deteriorate.


1966 ◽  
Vol 2 (7) ◽  
pp. 282
Author(s):  
A.M. Phahle ◽  
K.C. Kao ◽  
J.H. Calderwood

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