ChemInform Abstract: Palladium-Catalyzed Oxidative Carbonylative Coupling of Arylboronic Acids with Terminal Alkynes to Alkynones.

ChemInform ◽  
2015 ◽  
Vol 46 (1) ◽  
Author(s):  
Kishore Natte ◽  
Jianbin Chen ◽  
Helfried Neumann ◽  
Matthias Beller ◽  
Xiao-Feng Wu
2014 ◽  
Vol 12 (30) ◽  
pp. 5590-5593 ◽  
Author(s):  
Kishore Natte ◽  
Jianbin Chen ◽  
Helfried Neumann ◽  
Matthias Beller ◽  
Xiao-Feng Wu

The first example of palladium-catalyzed oxidative carbonylation of arylboronic acids with terminal alkynes has been developed. By an appropriate combination of a palladium salt, a ligand, and an oxidant, the desired alkynones were isolated in moderate to good yields.


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