A new bulky iminophosphonamide as an N,N′-chelating ligand: synthesis and structural characterization of heteroleptic group 13 element complexes

2014 ◽  
Vol 43 (44) ◽  
pp. 16880-16888 ◽  
Author(s):  
Billa Prashanth ◽  
Sanjay Singh
Keyword(s):  
Structural Characterization ◽  
Group 13 ◽  
Chelating Ligand ◽  
Ligand Synthesis

Coordination Frameworks Containing the Pyrimidin-4-olate Ligand. Synthesis, Thermal, Magnetic, andab InitioXRPD Structural Characterization of Nickel and Zinc Derivatives

2004 ◽  
Vol 43 (2) ◽  
pp. 473-481 ◽  
Author(s):  
Elisa Barea ◽  
Jorge A. R. Navarro ◽  
Juan M. Salas ◽  
Norberto Masciocchi ◽  
Simona Galli ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Ligand Synthesis ◽  
Coordination Frameworks

ChemInform Abstract: Synthesis and Solid-State Structural Characterization of a Series of Aqueous Heterometallic Tridecameric Group 13 Clusters.

ChemInform ◽  
2015 ◽  
Vol 46 (25) ◽  
pp. no-no
Author(s):  
Maisha K. Kamunde-Devonish ◽  
Dylan B. Fast ◽  
Zachary L. Mensinger ◽  
Jason T. Gatlin ◽  
Lev N. Zakharov ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Characterization ◽  
Group 13

Structural Characterization of Some Complexes of Group 13 Metal(III) Nitrates with N,N′-Bidentate Bases

2006 ◽  
Vol 59 (2) ◽  
pp. 147 ◽  
Author(s):  
Peter C. Junk ◽  
Brian W. Skelton ◽  
Allan H. White
Keyword(s):  
Rare Earth ◽  
Structural Characterization ◽  
Isomeric Form ◽  
Group 13 ◽  
The One

The structural characterization of several novel complexes of gallium(iii) and indium(iii) nitrates, crystallized with 2,2′-bipyridyl (bpy) and 1,10-phenanthroline (phen) from nitromethane solution, is presented. The adduct In(NO3)3:bpy (1:2) is of the form [(ONO2)(O2NO)2In(bpy)2], rather than [(ONO2)3ML2] as found for the larger M = Ln (rare earth), Bi, despite similar 2-symmetry. Several hydroxo-bridged dimers, [L2M(OH)2ML2](NO3)4(·S) are also presented, the cations all of the same isomeric form. [(ONO2)(bpy)In(OH)2In(bpy)(O2NO)], interestingly, displays two different forms within the one crystal, by virtue of different dispositions of the coordinated nitrate. The structures of related cis-[(phen)2GaBr2]Br(·S) and [(en)2In(OH)2In(en)2](NO3)4 (en = H2N(CH2)2NH2) are also described, the latter isomorphous with its cobalt(iii) counterpart.

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