Novel titanium complexes of a multidentate dicarbollide ligand. Synthesis and structural characterization of a constrained geometry complex

2003 ◽  
pp. 1364-1365 ◽  
Author(s):  
Young-Joo Lee ◽  
Jong-Dae Lee ◽  
Jaejung Ko ◽  
Sang-Hern Kim ◽  
Sang Ook Kang
Keyword(s):  
Structural Characterization ◽  
Titanium Complexes ◽  
Constrained Geometry ◽  
Ligand Synthesis

Synthesis and Structural Characterization of Hexacoordinate Silicon, Germanium, and Titanium Complexes of theE. coliSiderophore Enterobactin

2013 ◽  
Vol 19 (32) ◽  
pp. 10536-10542 ◽  
Author(s):  
Todor Baramov ◽  
Karlijn Keijzer ◽  
Elisabeth Irran ◽  
Eva Mösker ◽  
Mu-Hyun Baik ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Silicon Germanium ◽  
Titanium Complexes

Synthesis and structural characterization of titanium complexes containing a sulfinyl-bridged bis(phenolato) ligand

Polyhedron ◽  
1998 ◽  
Vol 17 (5-6) ◽  
pp. 943-946 ◽  
Author(s):  
Jun Okuda ◽  
Stefan Fokken ◽  
Hak-Chul Kang ◽  
Werner Massa
Keyword(s):  
Structural Characterization ◽  
Titanium Complexes

Molecular structures of a series of substituted bis(η5-cyclopentadienyl)titanium dihalides Cp R 2TiX 2 [X = F, Cl, Br and I; R = CHPh2, CH(p-Tol)2 and adamantyl]

2018 ◽  
Vol 74 (4) ◽  
pp. 442-451 ◽  
Author(s):  
Tim Oswald ◽  
Nicolai Lauterbach ◽  
Marc Schmidtmann ◽  
Rüdiger Beckhaus
Keyword(s):  
Structural Characterization ◽  
Antitumor Agents ◽  
Molecular Structures ◽  
Exchange Reactions ◽  
Titanium Complexes ◽  
Hydrogen Halides ◽  
Metathesis Reactions

Metallocene dihalides and derivatives thereof are of great interest as precursors for catalysts in polymerization reactions, as antitumor agents and, due to their increased stability, as suitable starting materials in salt metathesis reactions and the generation of metallocene fragments. We report the synthesis and structural characterization of a series of eleven substituted bis(η5-cyclopentadienyl)titanium dihalides, namely bis[η5-1-(diphenylmethyl)cyclopentadienyl]difluoridotitanium(IV), [Ti(C18H15)2F2], bis{η5-1-[bis(4-methylphenyl)methyl]cyclopentadienyl}difluoridotitanium(IV), [Ti(C20H19)2F2], and bis{η5-1-[bis(adamantan-2-yl)methyl]cyclopentadienyl}difluoridotitanium(IV), [Ti(C15H19)2F2], together with the bromide and iodide analogues, and the chloride analogues of the diphenylmethyl and adamantyl complexes. These eleven complexes were prepared by the reaction of the corresponding bis(η5:η1-pentafulvene)titanium complexes with different hydrogen halides (Cl, Br and I). The titanocene fluorides become available via chloride–fluoride exchange reactions.

Coordination Frameworks Containing the Pyrimidin-4-olate Ligand. Synthesis, Thermal, Magnetic, andab InitioXRPD Structural Characterization of Nickel and Zinc Derivatives

2004 ◽  
Vol 43 (2) ◽  
pp. 473-481 ◽  
Author(s):  
Elisa Barea ◽  
Jorge A. R. Navarro ◽  
Juan M. Salas ◽  
Norberto Masciocchi ◽  
Simona Galli ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Ligand Synthesis ◽  
Coordination Frameworks
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