Three new three-dimensional organic–inorganic hybrid compounds based on PMo12O40n− (n = 3 or 4) polyanions and CuI–pyrazine/CuI–pyrazine–Cl porous coordination polymers

2013 ◽  
Vol 42 (21) ◽  
pp. 7586 ◽  
Author(s):  
Ming-Li Qi ◽  
Kai Yu ◽  
Zhan-Hua Su ◽  
Chun-Xiao Wang ◽  
Chun-Mei Wang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Porous Coordination Polymers ◽  
Inorganic Hybrid ◽  
Hybrid Compounds

A three-dimensional hydrogen-bonded network in bis(4-hydroxyanilinium) selenate(VI) dihydrate

2009 ◽  
Vol 65 (3) ◽  
pp. o121-o122 ◽  
Author(s):  
Jan Janczak ◽  
Genivaldo Julio Perpétuo
Keyword(s):  
Crystal Engineering ◽  
Three Dimensional ◽  
The Other ◽  
Water Molecules ◽  
Inorganic Hybrid ◽  
Hybrid Compounds ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Hydroxy Groups ◽  
Oppositely Charged

The title compound, 2C6H8NO+·SeO42−·2H2O, contains 4-hydroxyanilinium cations, selenate(VI) anions and water molecules. One of the two independent cations is nearly planar (excluding the ammonium H atoms), while the other is markedly nonplanar, with the hydroxy and ammonium groups displaced from the plane of the benzene ring. This results from the antiparallel orientation of the cations, which interact through oppositely polarized ammonium and hydroxy groups. Ionic and hydrogen-bonding interactions join the oppositely charged units into a three-dimensional network. This work demonstrates the usefulness of 4-aminophenol in the crystal engineering of organic–inorganic hybrid compounds.

Cerium-based porous coordination polymers with hierarchical superstructures: fabrication, formation mechanism and their thermal conversion to hierarchical CeO2

2015 ◽  
Vol 2 (6) ◽  
pp. 567-575 ◽  
Author(s):  
Yong-Xia Zhao ◽  
Zhi-Wen Nie ◽  
Meng-Meng Shi ◽  
Cheng-Hui Zeng ◽  
Yuan Li ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Formation Mechanism ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Hierarchical Structures ◽  
Thermal Conversion ◽  
Porous Coordination Polymers ◽  
Polymer Precursors ◽  
Porous Coordination Polymer

Novel three-dimensional (3D) ceria hierarchical structures have been prepared via a thermolysis of the corresponding porous coordination polymer precursors.

Two Pillared Three-Dimensional Inorganic/Organic Hybrid Structures Composed of Bimetallic Layers Bridged by Exo-bidentate Ligands

2000 ◽  
Vol 658 ◽  
Author(s):  
Long Pan ◽  
Xiaoying Huang ◽  
Jing Li
Keyword(s):  
Three Dimensional ◽  
Bidentate Ligand ◽  
Organic Ligands ◽  
Hybrid Structures ◽  
Crystal Data ◽  
Bidentate Ligands ◽  
Inorganic Hybrid ◽  
Organic Hybrid ◽  
Hydrothermal Reactions ◽  
Hybrid Compounds

ABSTRACTThe hydrothermal reactions of Cu(NO3)2.3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1, a = 5.358(1), b = 5.603(1), c = 13.515(3) Å, α = 81.78(3), γ = 86.56(3), Å3 = 79.75(3)°, V = 394.91(13) Å3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) Å, β = 112.99(3)°, V = 2484.2(8) Å3, Z = 8.

scholarly journals Synthesis, X-ray diffraction and Hirshfeld surface analysis of two new hybrid dihydrate compounds: (C6H22N4)[SnCl6]Cl2·2H2O and (C8H24N4)[SnCl6]Cl2·2H2O

2018 ◽  
Vol 74 (2) ◽  
pp. 206-211
Author(s):  
Rafika Bouchene ◽  
Zohir Lecheheb ◽  
Ratiba Belhouas ◽  
Sofiane Bouacida
Keyword(s):  
Crystal Structures ◽  
Surface Analysis ◽  
Three Dimensional ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Water Molecules ◽  
X Ray Diffraction ◽  
Inorganic Hybrid ◽  
X Ray ◽  
Hybrid Compounds

Two new organic–inorganic hybrid compounds, triethylenetetraammonium hexachloridostannate (IV) dichloride dihydrate, (C6H22N4)[SnCl6]Cl2·2H2O, (I), and 1,4-bis(2-ammonioethyl)piperazin-1,4-diium hexachloridostannate (IV) dichloride dihydrate, (C8H24N4)[SnCl6]Cl2·2H2O, (II), have been synthesized from the same starting materials. In each case both the cations and anions are located about inversion centers. Their crystal structures exhibits alternating inorganic and organic stacking sheets in (I) and layers in (II), with Cl− ions and water molecules occupying the space in between. The cohesion of the three-dimensional frameworks are governed by N—H...Cl, N—H...O, C—H...Cl and O—H...Cl hydrogen bonds. Hirshfeld surface analysis of both crystal structures indicates that the H...Cl/Cl...H contacts exert an important influence on the stabilization of the packing.

ChemInform Abstract: A New Three-Dimensional Organic-Inorganic Hybrid Constructed from Keggin Polyoxometalates and CuI-Pyrazine Coordination Polymers.

ChemInform ◽  
2014 ◽  
Vol 45 (8) ◽  
pp. no-no
Author(s):  
Hongxun Yang ◽  
Jingchai Meng ◽  
Xiufei Sun ◽  
Lizhuang Chen ◽  
Dan Yang
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Inorganic Hybrid

Syntheses and Structures of Organic−Inorganic Hybrid Compounds Based on Metal−Fluconazole Coordination Polymers and the β-Mo8O26Anion

2007 ◽  
Vol 46 (20) ◽  
pp. 8283-8290 ◽  
Author(s):  
Li ◽  
Ya-Qian Lan ◽  
Jian-Fang Ma ◽  
Jin Yang ◽  
Xiao-Hong Wang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Inorganic Hybrid ◽  
Hybrid Compounds
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