Weak intermetallic bonding. A rare example of molecular stacking in a neutral square planar second-row transition-metal complex. X-Ray crystal structures of [Rh(cod)(Cl)(dmpH)] and [Rh(CO)2(Cl)(pzH)](cod = cyclo-octa-1,5-diene; dmpH = 3,5-dimethylpyrazole; pzH = pyrazole)

1983 ◽  
pp. 1525 ◽  
Author(s):  
Michael J. Decker ◽  
D. O. Kimberley Fjeldsted ◽  
Stephen R. Stobart ◽  
Michael J. Zaworotko
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Crystal Structures ◽  
Transition Metal Complex ◽  
X Ray ◽  
Square Planar ◽  
Molecular Stacking

Single-crystal x-ray and neutron diffraction studies of an .eta.2-dihydrogen transition-metal complex: trans-[Fe(.eta.2-H2)(H)(PPh2CH2CH2PPh2)2]BPh4

1989 ◽  
Vol 111 (24) ◽  
pp. 8823-8827 ◽  
Author(s):  
John S. Ricci ◽  
Thomas F. Koetzle ◽  
Maria T. Bautista ◽  
Theresa M. Hofstede ◽  
Robert H. Morris ◽  
...  
Keyword(s):  
Transition Metal ◽  
Neutron Diffraction ◽  
Metal Complex ◽  
Single Crystal ◽  
Transition Metal Complex ◽  
X Ray

scholarly journals Inelastic X-ray Scattering of a Transition-Metal Complex (FeCl4–): Vibrational Spectroscopy for All Normal Modes

2013 ◽  
Vol 52 (12) ◽  
pp. 6767-6769 ◽  
Author(s):  
Weibing Dong ◽  
Hongxin Wang ◽  
Marilyn M. Olmstead ◽  
James C. Fettinger ◽  
Jay Nix ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Vibrational Spectroscopy ◽  
Transition Metal Complex ◽  
Normal Modes ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Scattering

scholarly journals Crystal and molecular structure of the binuclear Rh(I) complex (μ-Cl)(μ-pz) [Rh(CO)2]2 (pz = pyrazolyl, N2C3H3). An example of molecular stacking via weak intermolecular interactions

1985 ◽  
Vol 63 (3) ◽  
pp. 688-691 ◽  
Author(s):  
Brenda M. Louie ◽  
Steven J. Rettig ◽  
Alan Storr ◽  
James Trotter
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Physical Properties ◽  
Transition Metal Complex ◽  
Crystal And Molecular Structure ◽  
Heavy Atom ◽  
Full Matrix ◽  
Weak Intermolecular Interactions ◽  
Molecular Stacking

Details of the synthesis and physical properties of (μ-Cl)(μ-pz)[Rh(CO)2]2 are given. Crystals of (μ-chloro) (μ-pyrazolyl)-bis(dicarbonylrhodiumd(I)) are monoclinic, a = 7.0970(8), b = 20.5184(10), c = 15.808(2) Å, β = 94.695(6)°, Z = 8, space group P21/c. The structure was solved by conventional heavy-atom methods and was refined by full-matrix least-squares procedures to R = 0.035 and Rw = 0.038 for 2949 reflections with I ≥ 3σ(I). The complex provides a rare example of molecular stacking in a binuclear transition metal complex with [Formula: see text] distances of 3.5107(8) and 3.6201(8) Å.

S4N4 und seine Derivate: α-FeCl3 · S4N4, ein Übergangsmetallkomplex mit dem S4N4-Ligand / S4N4 and its Derivatives: α-FeCl3 · S4N4, a Transition Metal Complex with the S4N4 Ligand

1980 ◽  
Vol 35 (7) ◽  
pp. 855-859 ◽  
Author(s):  
Ulf Thewalt
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Iron Atom ◽  
Transition Metal Complex ◽  
Lattice Parameters ◽  
Monoclinic Space Group ◽  
Space Group ◽  
X Ray

The adduct α-FeCl3 · S4N4 has been prepared from FeCl3 and S4N4 in CCl4. The new compound crystallizes in the monoclinic space group P 21/c with Z = 4 and lattice parameters a = 6.360(2), b = 13.066(4), c = 12.686(5) Å, and β = 99.43(3)°. An X-ray analysis shows that the S4N4 ring is bonded via one of its nitrogen atoms to the iron atom of the FeCl3 group and that the four ligand atoms around the iron atom form a tetrahedron. The structure of the complex is similar to the known structure of BF3 · S4N4

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