scholarly journals Crystal Structures, Photoluminescence, and Magnetism of Two Novel Transition-Metal Complex Cocrystals with Three-Dimensional H-Bonding Organic Framework or Alternating Noncovalent Anionic and Cationic Layers

ACS Omega ◽  
2019 ◽  
Vol 4 (7) ◽  
pp. 12230-12237 ◽  
Author(s):  
Xu-Sheng Gao ◽  
Hai-Jie Dai ◽  
Yuerou Tang ◽  
Mei-Juan Ding ◽  
Wen-Bo Pei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Crystal Structures ◽  
Transition Metal Complex ◽  
Three Dimensional ◽  
Organic Framework

A transition metal complex containing pyrazine-2,5-dicarboxylato bridging ligands: a novel three-dimensional manganese(II) compound

2003 ◽  
Vol 6 (9) ◽  
pp. 1224-1227 ◽  
Author(s):  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Antonio Luque ◽  
Urko Garcı́a-Couceiro ◽  
Juan P. Garcı́a-Teran ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Three Dimensional ◽  
Bridging Ligands

Incorporating a Transition Metal Complex into Polymeric Iodoplumbate: Structure Characterization, Properties and Theoretical Study of a Unprecedented Hybrid Semiconductor: {[Cu(en)2][Pb2I6]}n

2008 ◽  
Vol 61 (5) ◽  
pp. 391 ◽  
Author(s):  
Hao-Hong Li ◽  
Ling-Guo Sun ◽  
Zhi-Rong Chen ◽  
Yun-Jie Wang ◽  
Jun-Qian Li
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Density Functional ◽  
Transition Metal Complex ◽  
Density Functional Theory Calculation ◽  
Three Dimensional ◽  
Hybrid Structure ◽  
Structure Characterization ◽  
Dimensional Network ◽  
Theory Calculation

A hybrid semiconductor {[Cu(en)2][Pb2I6]}n (1) (en = ethylenediamine) templated by a transition metal complex was synthesized and structurally characterized. The title compound consists of discrete structure-directing molecules (transition metal complex) and an inorganic iodoplumbate polymer. The iodoplumbate polymer could be described as a three-dimensional network constructed from a [Pb2I8]n4– double chain bridged by iodine. [Cu(en)2]2+ structure-directing cations are discrete, and interact with the inorganic moiety by strong static attraction and the H-bond of N–H···I to give a so-called hybrid structure. Experimental and theoretical optical property investigations indicate that 1 possesses semiconductor properties. A density functional theory calculation was executed to probe the regulation effect on the introduction of a second metal.

Low-Dimensional Hybrid Cuprous Halides Directed by Transition Metal Complex: Syntheses, Crystal Structures, and Photocatalytic Properties

2015 ◽  
Vol 15 (11) ◽  
pp. 5416-5426 ◽  
Author(s):  
Xiao-Wu Lei ◽  
Cheng-Yang Yue ◽  
Jian-Qiang Zhao ◽  
Yong-Fang Han ◽  
Jiang-Tao Yang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Crystal Structures ◽  
Transition Metal Complex ◽  
Photocatalytic Properties ◽  
Low Dimensional

Synthesis, crystal structures of [M(tepa)]2(μ2-Sn2Se6)(M=Fe and Co), showing a selenidostannate bridge for transition metal complex cations

2007 ◽  
Vol 10 (3) ◽  
pp. 348-351 ◽  
Author(s):  
Jian Zhou ◽  
Yong Zhang ◽  
Ai-Bin Tang ◽  
Guo-Qing Bian ◽  
Ding-Xian Jia ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Crystal Structures ◽  
Transition Metal Complex
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