scholarly journals In situ study of the impact of acidic and neutral deposition pH on alkane phosphate film formation and stability on TiO2

RSC Advances ◽  
2013 ◽  
Vol 3 (8) ◽  
pp. 2581 ◽  
Author(s):  
Stephen A. Holt ◽  
Anton P. Le Brun ◽  
Andrew R. J. Nelson ◽  
Jeremy H. Lakey
Keyword(s):  
Film Formation ◽  
In Situ Study ◽  
The Impact ◽  
Phosphate Film

An in Situ Study of Mesostructured CTAB−Silica Film Formation during Dip Coating Using Time-Resolved SAXS and Interferometry Measurements

2002 ◽  
Vol 14 (2) ◽  
pp. 931-939 ◽  
Author(s):  
David Grosso ◽  
Florence Babonneau ◽  
Pierre-Antoine Albouy ◽  
Heinz Amenitsch ◽  
A. R. Balkenende ◽  
...  
Keyword(s):  
Film Formation ◽  
Dip Coating ◽  
Silica Film ◽  
Time Resolved ◽  
In Situ Study

In situ study of the film formation mechanism of organic–inorganic hybrid perovskite solar cells: controlling the solvate phase using an additive system

2020 ◽  
Vol 8 (16) ◽  
pp. 7695-7703 ◽  
Author(s):  
Sehyun Lee ◽  
Ming-Chung Tang ◽  
Rahim Munir ◽  
Dounya Barrit ◽  
Yeon-Ju Kim ◽  
...  
Keyword(s):  
Spin Coating ◽  
Film Formation ◽  
Perovskite Solar Cells ◽  
In Situ Study ◽  
Hybrid Perovskite ◽  
System P ◽  
Direct Formation ◽  
Film Formation Mechanism

The role of the additive and solvate phases in the direct formation of perovskite crystals was revealed by in situ analysis during spin-coating condition.

An in situ study of mesostructured CTAB-silica film formation using infrared ellipsometry: evolution of water content

2004 ◽  
Vol 455-456 ◽  
pp. 656-660 ◽  
Author(s):  
A. Brunet-Bruneau ◽  
A. Bourgeois ◽  
F. Cagnol ◽  
D. Grosso ◽  
C. Sanchez ◽  
...  
Keyword(s):  
Water Content ◽  
Film Formation ◽  
Silica Film ◽  
In Situ Study ◽  
Infrared Ellipsometry

Functional Poly(p-Xylylene)s via Chemical Reduction of Poly(p-Phenylene Vinylene)s

2019 ◽  
Author(s):  
Ain Uddin ◽  
Weifan Sang ◽  
Yong Gao ◽  
Kyle Plunkett
Keyword(s):  
Film Formation ◽  
Chemical Reduction ◽  
Water Soluble ◽  
Phenylene Vinylene ◽  
Polymer Modification ◽  
Polymer Backbone ◽  
Crosslinking Process ◽  
Conducting Membranes ◽  
In Situ Crosslinking

The synthesis of poly(p-xylylene)s (PPXs) with sidechains containing alkyl bromide functionality, and their post-polymer modification, is described. The PPXs were prepared by a diimide hydrogenation of poly(p-phenylene vinylene)s (PPVs) that were originally synthesized by a Gilch polymerization. The polymer backbone reduction was carried out with hydrazine hydrate in toluene at 80 °C to provide polymers with the sidechain-containing bromide functionality intact. To demonstrate post-polymer modification of the sidechains, the resulting PPX polymers were modified with trimethylamine to form tetraalkylammonium ion functionality and were evaluated as anion conducting membranes. While PPX homopolymers containing tetralkylammonium ions were completely water soluble and not able to form valuable films, PPX copolymers containing mixed tetraalkylammonium ions and hydrophobic chains were capable of film formation and alkaline stability. In addition, an in situ crosslinking process that used N,N,N',N'-tetramethyl-1,6-hexanediamine during the tetraalkylammonium formation of brominated PPX polymers was also evaluated and gave reasonable films with conductivities of ~10 mS-cm-1.

Functional Poly(p-Xylylene)s via Chemical Reduction of Poly(p-Phenylene Vinylene)s

2019 ◽  
Author(s):  
Ain Uddin ◽  
Weifan Sang ◽  
Yong Gao ◽  
Kyle Plunkett
Keyword(s):  
Film Formation ◽  
Chemical Reduction ◽  
Water Soluble ◽  
Phenylene Vinylene ◽  
Polymer Modification ◽  
Polymer Backbone ◽  
Crosslinking Process ◽  
Conducting Membranes ◽  
In Situ Crosslinking

The synthesis of poly(p-xylylene)s (PPXs) with sidechains containing alkyl bromide functionality, and their post-polymer modification, is described. The PPXs were prepared by a diimide hydrogenation of poly(p-phenylene vinylene)s (PPVs) that were originally synthesized by a Gilch polymerization. The polymer backbone reduction was carried out with hydrazine hydrate in toluene at 80 °C to provide polymers with the sidechain-containing bromide functionality intact. To demonstrate post-polymer modification of the sidechains, the resulting PPX polymers were modified with trimethylamine to form tetraalkylammonium ion functionality and were evaluated as anion conducting membranes. While PPX homopolymers containing tetralkylammonium ions were completely water soluble and not able to form valuable films, PPX copolymers containing mixed tetraalkylammonium ions and hydrophobic chains were capable of film formation and alkaline stability. In addition, an in situ crosslinking process that used N,N,N',N'-tetramethyl-1,6-hexanediamine during the tetraalkylammonium formation of brominated PPX polymers was also evaluated and gave reasonable films with conductivities of ~10 mS-cm-1.

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