In situ study of the film formation mechanism of organic–inorganic hybrid perovskite solar cells: controlling the solvate phase using an additive system

2020 ◽  
Vol 8 (16) ◽  
pp. 7695-7703 ◽  
Author(s):  
Sehyun Lee ◽  
Ming-Chung Tang ◽  
Rahim Munir ◽  
Dounya Barrit ◽  
Yeon-Ju Kim ◽  
...  

The role of the additive and solvate phases in the direct formation of perovskite crystals was revealed by in situ analysis during spin-coating condition.

2020 ◽  
Vol 8 (4) ◽  
pp. 1578-1603 ◽  
Author(s):  
Hanlin Hu ◽  
Mriganka Singh ◽  
Xuejuan Wan ◽  
Jiaoning Tang ◽  
Chih-Wei Chu ◽  
...  

In this review, we provide an in-depth overview of perovskite film formation mechanism and highlight the important role of nucleation/crystal growth in perovskite photovoltaics by using scalable solution deposition techniques.


2018 ◽  
Vol 90 (3) ◽  
pp. 507-522 ◽  
Author(s):  
Erica I. Parisi ◽  
Nicole Bonelli ◽  
Emiliano Carretti ◽  
Rodorico Giorgi ◽  
Gabriel M. Ingo ◽  
...  

AbstractThis paper presents an innovative poly(vinyl)alcohol-based film forming system, specifically devised for the controllable and selective cleaning of copper-based artifacts. Traditional cleaning procedures are commonly performed using mechanical and/or chemical methods. Unfortunately, both these methods present some limitations related to both the poor selectivity and invasiveness in case of the mechanical procedure, and to the scarce control over the involved reactions when dealing with a chemical approach. The innovative system proposed in this work allows combining the advantages of chemical and mechanical treatments thanks to the confinement of a complexing agent (EDTA) within a fluid, polymeric matrix, that is able to form a solid thin film upon drying. After treatment, the polymeric film can be completely removed from the artwork through a gentle peeling action. In this contribution, the film formation mechanism was investigated by means of thermal analysis and rheology; the role of plasticizers, volatile solvent fraction, and quantity of loaded EDTA is also discussed. Finally, the results of cleaning tests performed on artificially aged samples, and on a real case study, the “Fontana dei Mostri Marini” by Pietro Tacca in Florence, are presented.


2020 ◽  
Vol 13 (11) ◽  
pp. 4344-4352
Author(s):  
Ning Yang ◽  
Cheng Zhu ◽  
Yihua Chen ◽  
Huachao Zai ◽  
Chenyue Wang ◽  
...  

An in situ cross-linked 1D/3D perovskite heterostructure achieved a perovskite solar cell with a 21.19% PCE and operational stability over 3000 hours.


2018 ◽  
Vol 71 ◽  
pp. 49-53 ◽  
Author(s):  
T.T. Maske ◽  
N.K. Kuper ◽  
A.C.C. Hollanders ◽  
E.M. Bronkhorst ◽  
M.S. Cenci ◽  
...  

2020 ◽  
Vol 3 (6) ◽  
pp. 5987-5994 ◽  
Author(s):  
Lin Song ◽  
Martin A. Niedermeier ◽  
Volker Körstgens ◽  
Franziska C. Löhrer ◽  
Yonghua Chen ◽  
...  

2002 ◽  
Vol 14 (2) ◽  
pp. 931-939 ◽  
Author(s):  
David Grosso ◽  
Florence Babonneau ◽  
Pierre-Antoine Albouy ◽  
Heinz Amenitsch ◽  
A. R. Balkenende ◽  
...  

2017 ◽  
Vol 32 (10) ◽  
pp. 1899-1907 ◽  
Author(s):  
Dounya Barrit ◽  
Arif D. Sheikh ◽  
Rahim Munir ◽  
Jérémy M. Barbé ◽  
Ruipeng Li ◽  
...  

Abstract


2017 ◽  
Vol 5 (35) ◽  
pp. 18561-18568 ◽  
Author(s):  
Amitava Banerjee ◽  
Sudip Chakraborty ◽  
Rajeev Ahuja

Guanidinium lead iodide (GAPbI3) has been synthesized experimentally, but stability remains an issue, which can be modulated by the insertion of bromine (Br) into the system.


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