Layered double hydroxides as carriers for quantum dots@silica nanospheres

Nanoscale ◽  
2012 ◽  
Vol 4 (17) ◽  
pp. 5409 ◽  
Author(s):  
Georgiana Stoica ◽  
Iván Castelló Serrano ◽  
Albert Figuerola ◽  
Irati Ugarte ◽  
Roberto Pacios ◽  
...  
2013 ◽  
Author(s):  
Georgiana Stoica ◽  
Iván Castelló Serrano ◽  
Emilio Palomares

2017 ◽  
Vol 5 (14) ◽  
pp. 3473-3479 ◽  
Author(s):  
Zhixiong Li ◽  
Yuqiong Zhou ◽  
Dongpeng Yan ◽  
Min Wei

Electrochemiluminescence (ECL) resonance energy transfer (ERET) systems have shown excellent potential in analysis and detection fields because of the supersensitivity, high level of controllability, and amplified signal.


2017 ◽  
Vol 5 (20) ◽  
pp. 5024-5030 ◽  
Author(s):  
Jieyuan Liu ◽  
Guocheng Lv ◽  
Wenlong Gu ◽  
Zhaohui Li ◽  
Aiwei Tang ◽  
...  

A remarkable improvement in luminescence intensity was achieved by immobilizing quantum dots on the surface of layered double hydroxides, for the detection of heavy metals in real water samples.


2015 ◽  
Vol 6 (8) ◽  
pp. 4846-4850 ◽  
Author(s):  
Liqing Song ◽  
Jingjing Shi ◽  
Jun Lu ◽  
Chao Lu

We observe the structure of single-layered graphene quantum dots prepared in the 2D confined space of layered double hydroxides.


2021 ◽  
Author(s):  
Lili Song ◽  
Shifan Zhu ◽  
Le Tong ◽  
Wandi Wang ◽  
Chun Ouyang ◽  
...  

The rapid activity degradation of layered double hydroxides (LDHs) is caused by the mismatch of surface component and construction. Herein, MXene quantum dots (MQDs) rivets are used to adjust the...


2018 ◽  
Author(s):  
Diana Ainembabazi ◽  
Nan An ◽  
Jinesh Manayil ◽  
Kare Wilson ◽  
Adam Lee ◽  
...  

<div> <p>The synthesis, characterization, and activity of Pd-doped layered double hydroxides (Pd-LDHs) for for acceptorless amine dehydrogenation is reported. These multifunctional catalysts comprise Brønsted basic and Lewis acidic surface sites that stabilize Pd species in 0, 2+, and 4+ oxidation states. Pd speciation and corresponding cataytic performance is a strong function of metal loading. Excellent activity is observed for the oxidative transamination of primary amines and acceptorless dehydrogenation of secondary amines to secondary imines using a low Pd loading (0.5 mol%), without the need for oxidants. N-heterocycles, such as indoline, 1,2,3,4-tetrahydroquinoline, and piperidine, are dehydrogenated to the corresponding aromatics with high yields. The relative yields of secondary imines are proportional to the calculated free energy of reaction, while yields for oxidative amination correlate with the electrophilicity of primary imine intermediates. Reversible amine dehydrogenation and imine hydrogenation determine the relative imine:amine selectivity. Poisoning tests evidence that Pd-LDHs operate heterogeneously, with negligible metal leaching; catalysts can be regenerated by acid dissolution and re-precipitation.</p> </div> <br>


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