On the benefit of the Canadian Small Lake Model to better represent the impact of small natural lakes on GEM-Hydro streamflow simulations.

<p>This study aims at assessing the impact of a new lake model on streamflow simulations performed with the GEM-Hydro hydrologic model developed at ECCC. GEM-Hydro is at the heart of the National Surface and River Prediction System (NSRPS) which ECCC uses to forecast river flows over most of Canada. The GEM-Hydro model mainly consists of the GEM-Surf component to represent surface processes, and of the Watroute model to represent river and lake routing, in order to perform streamflow simulations and forecasts. The surface component of GEM-Hydro can simulate 5 different types of surfaces.  Currently, the water tile consists of a very simple algorithm which, in terms of water balance, consists of producing runoff fluxes simply equal to precipitation minus evaporation. This runoff over water surfaces is then provided as input, along with runoff and drainage generated over other surface tiles, to the Watroute model. The Watroute version used in GEM-Hydro currently only represents major lakes (area greater than 100km<sup>2</sup>) along the river networks, and does not represent the impact that small lakes can have on streamflow, which mainly consists in slowing down runoff before it reaches the main streams of the network.</p><p>Recently, the Canadian Small Lake Model (CSLM) was implemented in the surface component of GEM-Hydro to represent the energy and water balance over water tiles more accurately. So far, CSLM simulations have been shown promising in terms of evaporation, ice cover, absolute and dew point temperature simulations, compared with the former algorithm used over water. However, the impact of CSLM on the resulting streamflow simulations performed with GEM-Hydro has not been evaluated yet. This study aims first at evaluating the impact of CSLM on streamflow simulations, and secondly at testing different CSLM configurations as well as different coupling strategies with Watroute, with the objective of finding the best set up for the prediction of streamflow in Canada. For example, overland runoff generated by the land tile can be provided to the water tile of the same grid point in different ways, and the outflow computed at the outlet of the water tile can be computed with different parameters. Moreover, different outflow computations have to be taken into account depending on if the water tile of a grid point represents subgrid-scale lakes, or if on the contrary it belongs to a lake spanning over multiple model grid points.</p><p>To do so, different GEM-Hydro open-loop simulations have been performed on the Lake of the Woods watershed, located in Canada, with and without CSLM to represent water tiles. The CSLM configurations leading to the best results are presented here. CSLM simulations are also evaluated in terms of surface fluxes, to ensure that the main purpose of the model, which is to improve surface fluxes to ultimately improve atmospheric forecasts, is preserved, compared to the default configuration of the model. Ideas for further improving the coupling between the GEM-Hydro surface and routing components, in terms of lake processes, are also presented and will be tested in future work.</p>

Ensemble-based data assimilation of atmospheric boundary layer observations improves the soil moisture analysis

We revise the potential of assimilating atmospheric boundary layer observations into the soil moisture. Previous studies often stated a negative assimilation impact of boundary layer observations on the soil moisture analysis, but recent developments in physically-consistent hydrological model systems and ensemble-based data assimilation lead to an emerging potential of boundary layer observations for land surface data assimilation. To explore this potential, we perform idealized twin experiments for a seven-day period in Summer 2015 with a coupled atmosphere-land modelling platform. We use TerrSysMP for these limited-area simulations with a horizontal resolution 1.0 km in the land surface component. We assimilate sparse synthetic 2-metre-temperature observations into the land surface component and update the soil moisture with a localized Ensemble Kalman filter. We show a positive assimilation impact of these observations on the soil moisture analysis during day-time and a neutral impact during night. Furthermore, we find that hourly-filtering with a three-dimensional Ensemble Kalman filter results in smaller errors than daily-smoothing with a one-dimensional Simplified Extended Kalman filter, whereas the Ensemble Kalman filter additionally allows us to directly assimilate boundary layer observations without an intermediate optimal interpolation step. We increase the physical consistency in the analysis for the land surface and boundary by updating the atmospheric temperature together with the soil moisture, which as a consequence further reduces errors in the soil moisture analysis. Based on these results, we conclude that we can merge the decoupled data assimilation cycles for the land surface and the atmosphere into one single cycle with hourly-like update steps.

MXene quantum dots rivet reinforced Ni-Co LDH for boosting electrochemical activity and cycling stability

The rapid activity degradation of layered double hydroxides (LDHs) is caused by the mismatch of surface component and construction. Herein, MXene quantum dots (MQDs) rivets are used to adjust the...

Модель влияния смещения затвора при ионизирующем облучении МОП-структур

The new quantitative model of influence of gate bias on the threshold shift of MOS-structures at the ionizing radiation which is based on the accounting of holes trapping in a thin border layer of gate dielectric on interface with a silicon substrate is developed. The model allows to describe the smooth growth of threshold shift with gate bias – approximately linear from a dose for a surface component and nonlinear for a volume component. The threshold shift at a negative gate bias is modelled on the basis of the accounting of holes generation at ionizing radiation in the border layer.

AlInSb/InSb-гетероструктуры для ИК-фотоприемников, выращенные методом молекулярно-лучевой эпитаксии

A photodetector heterostructure based on AlInSb / InSb grown by molecular beam epitaxy was presented. Mesastructures of various diameters were fabricated and the temperature dependence of the dark current was measured. It was shown that the built-in barrier blocks the flow of the main charge carriers, thereby reducing the dark current density, in comparison with the pin structure based on InSb. By measuring the dependence of the dark current on the size of the mesastructure, it was shown that the bulk component of the current prevails over the surface component.

Study of Singlet Oxygen Dynamics on Silicon Polymer Matrix

We report a detailed analysis of singlet oxygen generated from the photofunctional polymer film (PFPF) matrix which is the silicone polymer film (PDMS) embedded with a photosensitizer. Activation and deactivation dynamics of singlet oxygen generated from PFPFs were investigated with time-resolved phosphorescence spectroscopy. The singlet oxygen generated from PFPFs was dissipated into three different regions of the polymer matrix; the inside (component A), the surface (component B), and the outside (component C). According to the deactivation dynamics of singlet oxygen in the polymer matrix, the components B and C are expected to be more important for various applications.