Dinuclear aluminum complexes supported by amino- or imino-phenolate ligands: synthesis, structures, and ring-opening polymerization catalysis of rac-lactide

2013 ◽  
Vol 42 (11) ◽  
pp. 3860 ◽  
Author(s):  
Xiao-Feng Yu ◽  
Zhong-Xia Wang
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Polymerization Catalysis ◽  
Aluminum Complexes ◽  
Phenolate Ligands

Aluminum complexes containing biphenolate phosphine ligands: synthesis and living ring-opening polymerization catalysis

2016 ◽  
Vol 45 (40) ◽  
pp. 15951-15962 ◽  
Author(s):  
Yu-Ning Chang ◽  
Pei-Ying Lee ◽  
Xue-Ru Zou ◽  
Han-Fan Huang ◽  
Yi-Wei Chen ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Phosphine Ligands ◽  
Polymerization Catalysis ◽  
Aluminum Complexes

The first examples of aluminum complexes containing biphenolate phosphine ligands are prepared, structurally characterized, and demonstrated to have catalytic competence in the living ring-opening (co)polymerization of ε-caprolactone and rac-lactide.

scholarly journals Synthesis of aluminum complexes supported by 2-(1,10-phenanthrolin-2-yl)phenolate ligands and their catalysis in the ring-opening polymerization of cyclic esters

RSC Advances ◽  
2017 ◽  
Vol 7 (44) ◽  
pp. 27177-27188 ◽  
Author(s):  
Xiang-Xin Zheng ◽  
Zhong-Xia Wang
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Block Copolymerization ◽  
Cyclic Esters ◽  
Aluminum Complexes ◽  
Phenolate Ligands

Phenanthroline-phenolate based N,N,O-chelate aluminum complexes were demonstrated to catalyze the ROP of ε-caprolactone, rac-lactide, and rac-β-butyrolactone, as well as their block copolymerization.

Synthesis and characterization of neutral and cationic aluminum complexes supported by a furfuryl-containing aminophenolate ligand for ring-opening polymerization of ε-caprolactone

2018 ◽  
Vol 42 (11) ◽  
pp. 8374-8383 ◽  
Author(s):  
Jiraya Kiriratnikom ◽  
Sucheewin Chotchatchawankul ◽  
Setsiri Haesuwannakij ◽  
Supavadee Kiatisevi ◽  
Khamphee Phomphrai
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Synthesis And Characterization ◽  
Aluminum Complexes

Mononuclear aluminum complexes supported by novel furfuryl-containing aminophenolate ligand are reported along with CL polymerization.

Synthesis of biodegradable and biorenewable polylactides initiated by aluminum complexes bearing m-xylylenediamine derivatives via the ring-opening polymerization of lactides

2019 ◽  
Vol 43 (18) ◽  
pp. 6943-6950 ◽  
Author(s):  
Dongni Li ◽  
Bo Gao ◽  
Qian Duan
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes ◽  
Lactide Polymerization

Aluminum complexes derived from m-xylylenediamine were synthesized and investigated as initiators for l-lactide and rac-lactide polymerization.

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