Aluminum complexes containing biphenolate phosphine ligands: synthesis and living ring-opening polymerization catalysis

2016 ◽  
Vol 45 (40) ◽  
pp. 15951-15962 ◽  
Author(s):  
Yu-Ning Chang ◽  
Pei-Ying Lee ◽  
Xue-Ru Zou ◽  
Han-Fan Huang ◽  
Yi-Wei Chen ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Phosphine Ligands ◽  
Polymerization Catalysis ◽  
Aluminum Complexes

The first examples of aluminum complexes containing biphenolate phosphine ligands are prepared, structurally characterized, and demonstrated to have catalytic competence in the living ring-opening (co)polymerization of ε-caprolactone and rac-lactide.

Synthesis and characterization of neutral and cationic aluminum complexes supported by a furfuryl-containing aminophenolate ligand for ring-opening polymerization of ε-caprolactone

2018 ◽  
Vol 42 (11) ◽  
pp. 8374-8383 ◽  
Author(s):  
Jiraya Kiriratnikom ◽  
Sucheewin Chotchatchawankul ◽  
Setsiri Haesuwannakij ◽  
Supavadee Kiatisevi ◽  
Khamphee Phomphrai
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Synthesis And Characterization ◽  
Aluminum Complexes

Mononuclear aluminum complexes supported by novel furfuryl-containing aminophenolate ligand are reported along with CL polymerization.

Synthesis of biodegradable and biorenewable polylactides initiated by aluminum complexes bearing m-xylylenediamine derivatives via the ring-opening polymerization of lactides

2019 ◽  
Vol 43 (18) ◽  
pp. 6943-6950 ◽  
Author(s):  
Dongni Li ◽  
Bo Gao ◽  
Qian Duan
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes ◽  
Lactide Polymerization

Aluminum complexes derived from m-xylylenediamine were synthesized and investigated as initiators for l-lactide and rac-lactide polymerization.

Synthesis of dinuclear aluminum complexes bearing bis-phenolate ligand and application in ring-opening polymerization of ε-caprolactone

2017 ◽  
Vol 41 (6) ◽  
pp. 2358-2363 ◽  
Author(s):  
Jie Zhang ◽  
Shaofeng Liu ◽  
Weiwei Zuo ◽  
Hongqi Ye ◽  
Zhibo Li
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes

Dinuclear zwitterionic aluminum complexes were prepared and applied as efficient catalysts toward ROP of ε-CL in a controlled manner.

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