Aluminum Complexes Stabilized by Piperazidine-Bridged Bis(phenolate) Ligands: Syntheses, Structures, and Application in the Ring-Opening Polymerization of ε-Caprolactone

2012 ◽  
Vol 30 (3) ◽  
pp. 609-615 ◽  
Author(s):  
Wenyi Li ◽  
Yingming Yao ◽  
Yong Zhang ◽  
Qi Shen
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes ◽  
Phenolate Ligands

scholarly journals Synthesis of aluminum complexes supported by 2-(1,10-phenanthrolin-2-yl)phenolate ligands and their catalysis in the ring-opening polymerization of cyclic esters

RSC Advances ◽  
2017 ◽  
Vol 7 (44) ◽  
pp. 27177-27188 ◽  
Author(s):  
Xiang-Xin Zheng ◽  
Zhong-Xia Wang
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Block Copolymerization ◽  
Cyclic Esters ◽  
Aluminum Complexes ◽  
Phenolate Ligands

Phenanthroline-phenolate based N,N,O-chelate aluminum complexes were demonstrated to catalyze the ROP of ε-caprolactone, rac-lactide, and rac-β-butyrolactone, as well as their block copolymerization.

Synthesis and characterization of neutral and cationic aluminum complexes supported by a furfuryl-containing aminophenolate ligand for ring-opening polymerization of ε-caprolactone

2018 ◽  
Vol 42 (11) ◽  
pp. 8374-8383 ◽  
Author(s):  
Jiraya Kiriratnikom ◽  
Sucheewin Chotchatchawankul ◽  
Setsiri Haesuwannakij ◽  
Supavadee Kiatisevi ◽  
Khamphee Phomphrai
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Synthesis And Characterization ◽  
Aluminum Complexes

Mononuclear aluminum complexes supported by novel furfuryl-containing aminophenolate ligand are reported along with CL polymerization.

Synthesis of biodegradable and biorenewable polylactides initiated by aluminum complexes bearing m-xylylenediamine derivatives via the ring-opening polymerization of lactides

2019 ◽  
Vol 43 (18) ◽  
pp. 6943-6950 ◽  
Author(s):  
Dongni Li ◽  
Bo Gao ◽  
Qian Duan
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes ◽  
Lactide Polymerization

Aluminum complexes derived from m-xylylenediamine were synthesized and investigated as initiators for l-lactide and rac-lactide polymerization.

Synthesis of dinuclear aluminum complexes bearing bis-phenolate ligand and application in ring-opening polymerization of ε-caprolactone

2017 ◽  
Vol 41 (6) ◽  
pp. 2358-2363 ◽  
Author(s):  
Jie Zhang ◽  
Shaofeng Liu ◽  
Weiwei Zuo ◽  
Hongqi Ye ◽  
Zhibo Li
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes

Dinuclear zwitterionic aluminum complexes were prepared and applied as efficient catalysts toward ROP of ε-CL in a controlled manner.

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