The bis(hydrogenheptaphosphide)iron(ii) dianion: a Zintl ion analogue of ferrocene?

2011 ◽  
Vol 47 (14) ◽  
pp. 4111 ◽  
Author(s):  
Caroline M. Knapp ◽  
Joseph S. Large ◽  
Nicholas H. Rees ◽  
Jose M. Goicoechea
Keyword(s):  
Zintl Ion

Synthesis and structure of binary copper/silver–arsenic clusters derived from Zintl ion As 7 3–

2021 ◽  
Author(s):  
Wei‐Qiang Zhang ◽  
Nikolay V. Tkachenko ◽  
Lei Qiao ◽  
Alexander I. Boldyrev ◽  
Zhong‐Ming Sun
Keyword(s):  
Zintl Ion

[Ni5Sb17]4-Transition-Metal Zintl Ion Complex:  Crossing the Zintl Border in Molecular Intermetalloid Clusters

2007 ◽  
Vol 46 (4) ◽  
pp. 1036-1038 ◽  
Author(s):  
Melanie J. Moses ◽  
James C. Fettinger ◽  
Bryan W. Eichhorn
Keyword(s):  
Transition Metal ◽  
Zintl Ion

scholarly journals Unique reactivity of B in B[Ge9Y3]3 (Y = H, CH3, BO, CN): formation of a Lewis base

2019 ◽  
Vol 21 (42) ◽  
pp. 23301-23304
Author(s):  
G. Naaresh Reddy ◽  
Rakesh Parida ◽  
R. Inostroza-Rivera ◽  
Arindam Chakraborty ◽  
Puru Jena ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Lewis Base ◽  
Lewis Acidity ◽  
Boron Compounds ◽  
Zintl Ion ◽  
Acid Nature ◽  
Boron Center

Boron compounds usually exhibit Lewis acidity at the boron center due to the presence of vacant p-orbitals. But using Zintl-ion based groups (Ge9Y3, Y = H, CH3, BO, CN), we can alter Lewis acid nature of B to a Lewis base.

scholarly journals Structural isomerism in the [(Ni@Sn9)In(Ni@Sn9)]5− Zintl ion

2019 ◽  
Vol 48 (42) ◽  
pp. 15888-15895
Author(s):  
Chao Zhang ◽  
Harry W. T. Morgan ◽  
Zi-Chuan Wang ◽  
Chao Liu ◽  
Zhong-Ming Sun ◽  
...  
Keyword(s):  
The Other ◽  
Indium Atom ◽  
Structural Isomerism ◽  
Zintl Ion

A new Zintl cluster, [(Ni@Sn9)In(Ni@Sn9)]5−, has been isolated in two distinct isomeric forms, one where both Ni@Sn9 units are coordinated to the bridging indium atom in an η3- mode, the other where one is η3- and the other η4-.

Significant geometry and charge difference between the E54− bare clusters of group 14 Zintl anions and their coordinated form in [E5{M(CO)3}2]4− (E = Si, Ge, Sn, Pb; M = Cr, Mo, W) complexes

2019 ◽  
Vol 43 (20) ◽  
pp. 7797-7805 ◽  
Author(s):  
Yasin Gholiee ◽  
Sadegh Salehzadeh ◽  
Shiva Khodaveisi
Keyword(s):  
Negative Charge ◽  
Metal Carbonyls ◽  
Group 14 ◽  
Ring Form ◽  
Zintl Ion

It is shown that while none of the E5n (E = Si, Ge, Sn, Pb; n = 0, 2−, 4−) bare clusters can be stabilized in planar pentagon (D5h) geometry, E54− ions as a five-membered planar ring form stable complexes with two {M(CO)3} (M = Cr, Mo, W) metal carbonyls. Interestingly, the negative charge of all [E5{M(CO)3}2]4− complexes is distributed on two {M(CO)3} fragments rather than the coordinated Zintl ion.

scholarly journals [Ni5Sb17]4- Transition-Metal Zintl Ion Complex: Crossing the Zintl Border in Molecular Intermetalloid Clusters.

ChemInform ◽  
2007 ◽  
Vol 38 (21) ◽  
Author(s):  
Melanie J. Moses ◽  
James C. Fettinger ◽  
Bryan W. Eichhorn
Keyword(s):  
Transition Metal ◽  
Zintl Ion

Probing Individual Steps of Dynamic Exchange with31P EXSY NMR Spectroscopy:  Synthesis and Characterization of the [E7PtH(PPh3)]2-Zintl Ion Complexes [E = P, As]

2000 ◽  
Vol 122 (45) ◽  
pp. 11101-11107 ◽  
Author(s):  
Banu Kesanli ◽  
Scott Charles ◽  
Yiu-Fai Lam ◽  
Simon G. Bott ◽  
James Fettinger ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Synthesis And Characterization ◽  
Dynamic Exchange ◽  
Zintl Ion
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