Adsorption of carbon monoxide on smaller gold-cluster anions in an atmospheric-pressure flow-reactor: temperature and humidity dependence

2005 ◽  
Vol 7 (5) ◽  
pp. 930 ◽  
Author(s):  
William T. WallaceCurrent address: Department ◽  
Richard B. WyrwasCurrent address: Department o ◽  
Andrew J. Leavitt ◽  
Robert L. Whetten
Keyword(s):  
Carbon Monoxide ◽  
Atmospheric Pressure ◽  
Flow Reactor ◽  
Gold Cluster ◽  
Cluster Anions ◽  
Pressure Flow ◽  
Temperature And Humidity ◽  
Reactor Temperature ◽  
Humidity Dependence

Analogues of the active and inactive sodium carbonate

1982 ◽  
Vol 47 (12) ◽  
pp. 3348-3361 ◽  
Author(s):  
Erich Lippert ◽  
Karel Mocek ◽  
Emerich Erdös
Keyword(s):  
Thermal Decomposition ◽  
Time Dependence ◽  
Water Vapour ◽  
Sulphur Dioxide ◽  
Atmospheric Pressure ◽  
Flow Reactor ◽  
Kinetic Measurements ◽  
Sodium Potassium ◽  
Alkaline Metals ◽  
Hydrogen Carbonates

The reactivity of the anhydrous carbonates of alkaline metals with sulphur dioxide has been studied experimentally in dependence both on the nature of the cation and on the way of preparation of the anhydrous carbonate. The carbonates were prepared either by thermal decomposition of hydrogen carbonates or by thermal dehydration of carbonate hydrates. The carbonates of lithium, sodium, potassium, rubidium and caesium have been investigated. Kinetic measurements were carried out in a flow reactor in the integral regime at 423 K under atmospheric pressure, with a gas containing 0.2 vol.% of sulphur dioxide and 2.0 vol.% of water vapour in the nitrogen as a carrier gas. The reactivities have been compared on the basis of time dependence of the conversion of carbonate to sulphite.

Kinetics of the catalytic hydrodesulphurization reaction system; hydrogenolysis of thiophene

1980 ◽  
Vol 45 (10) ◽  
pp. 2728-2741 ◽  
Author(s):  
Pavel Fott ◽  
Petr Schneider
Keyword(s):  
Atmospheric Pressure ◽  
Active Sites ◽  
Flow Reactor ◽  
Kinetic Equations ◽  
Reaction System ◽  
Reaction Products ◽  
Molybdenum Catalyst ◽  
Cobalt Molybdenum Catalyst ◽  
Kinetics Of ◽  
Reaction Schemes

Kinetics have been studied of the reaction system taking place during the reaction of thiophene on the cobalt-molybdenum catalyst in a gradientless circulation flow reactor at 360 °C and atmospheric pressure. Butane has been found present in a small amount in the reaction products even at very low conversion. In view of this, consecutive and parallel-consecutive (triangular) reaction schemes have been proposed. In the former scheme the appearance of butane is accounted for by rate of desorption of butene being comparable with the rate of its hydrogenation. According to the latter scheme part of the butane originates from thiophene via a different route than through hydrogenation of butene. Analysis of the kinetic data has revealed that the reaction of thiophene should be considered to take place on other active sites than that of butene. Kinetic equations derived on this assumption for the consecutive and the triangular reaction schemes correlate experimental data with acceptable accuracy.

Thermocatalytic Hydrodeoxygenation and Depolymerization of Waste Lignin to Oxygenates and Biofuels in a Continuous Flow Reactor at Atmospheric Pressure

2020 ◽  
Vol 8 (35) ◽  
pp. 13195-13205 ◽  
Author(s):  
Swathi Mukundan ◽  
Daria Boffito ◽  
Abhijit Shrotri ◽  
Luqman Atanda ◽  
Jorge Beltramini ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Continuous Flow ◽  
Flow Reactor ◽  
Continuous Flow Reactor

scholarly journals Climatological and statistical characteristics of the Haines Index for North America

2007 ◽  
Vol 16 (2) ◽  
pp. 139 ◽  
Author(s):  
Julie A. Winkler ◽  
Brian E. Potter ◽  
Dwight F. Wilhelm ◽  
Ryan P. Shadbolt ◽  
Krerk Piromsopa ◽  
...  
Keyword(s):  
North America ◽  
Spatial Variability ◽  
Atmospheric Pressure ◽  
Statistical Characteristics ◽  
Potential Contribution ◽  
Extensive Analysis ◽  
Temperature And Humidity ◽  
Humidity Measurements ◽  
Operational Tool

The Haines Index is an operational tool for evaluating the potential contribution of dry, unstable air to the development of large or erratic plume-dominated wildfires. The index has three variants related to surface elevation, and is calculated from temperature and humidity measurements at atmospheric pressure levels. To effectively use the Haines Index, fire forecasters and managers must be aware of the climatological and statistical characteristics of the index for their location. However, a detailed, long-term, and spatially extensive analysis of the index does not currently exist. To meet this need, a 40-year (1961–2000) climatology of the Haines Index was developed for North America. The climatology is based on gridded (2.5° latitude × 2.5° longitude) temperature and humidity fields from the NCEP/NCAR reanalysis. The climatology illustrates the large spatial variability in the Haines Index both within and between regions using the different index variants. These spatial variations point to the limitations of the index and must be taken into account when using the Haines Index operationally.

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