Femtosecond dynamics of hydrogen migration and internal conversion in cycloheptatriene and derivatives studied by intense-field dissociative ionization

1999 ◽  
Vol 1 (7) ◽  
pp. 1431 ◽  
Author(s):  
S A. Trushin ◽  
S Diemer ◽  
W Fu ◽  
K L. Kompa ◽  
W E. Schmid
RSC Advances ◽  
2019 ◽  
Vol 9 (29) ◽  
pp. 16683-16689 ◽  
Author(s):  
Hua Wu ◽  
Yuanxin Xue ◽  
Junqing Wen ◽  
Hui Wang ◽  
Qingfei Fan ◽  
...  

Hydrogen migration processes of methanol monocation CH3OH+ to H3+, COH+, H2O+ and CH2+ were studied theoretically and experimentally.


1992 ◽  
Vol 69 (18) ◽  
pp. 2646-2649 ◽  
Author(s):  
W. T. Hill ◽  
J. Zhu ◽  
D. L. Hatten ◽  
Y. Cui ◽  
J. Goldhar ◽  
...  

1998 ◽  
Vol 108 (10) ◽  
pp. 3922-3931 ◽  
Author(s):  
Eric Charron ◽  
Annick Suzor-Weiner

1983 ◽  
Vol 38 (5) ◽  
pp. 635-638 ◽  
Author(s):  
Bernhard Ciommer ◽  
Helmut Schwarz

Abstract The long-sought ethylen fluoronium ion (2) is generated as an intermediate in the dissociative ionization of 1-fluoro-2-(p-methyl)phenoxy ethane (4). However, prior to collisionally induced dissociation 2 undergoes ring-opening, associated with hydrogen migration, to form 1-fluoroethyl cation (3). Other decomposition pathways of the molecular ions of 4 involve (i) direct formation of 3 via a combination of C-O-cleavage (loss of ArO -) and [1,2] hydrogen migration (18%) and (ii) complete positional loss of the a-and β-methylene hydrogen atoms (34%). The remaining 48% of the molecular ions of 4 dissociate via anchimeric assistance of the fluorine in the elimination of ArO·, thus giving rise to the formation of 2.


1987 ◽  
Vol 58 (23) ◽  
pp. 2424-2427 ◽  
Author(s):  
L. J. Frasinski ◽  
K. Codling ◽  
P. Hatherly ◽  
J. Barr ◽  
I. N. Ross ◽  
...  

1964 ◽  
Vol 2 (4) ◽  
pp. 241-262 ◽  
Author(s):  
S. Forberg ◽  
E. Odeblad ◽  
R. Söremark ◽  
S. Ullberg

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