Substituent Effects of the Backbone in α-Diimine Palladium Catalysts on Homo- and Copolymerization of Ethylene with Methyl Acrylate

Lihua Guo; Haiyang Gao; Qirui Guan; Haibin Hu; Juean Deng; Jun Liu; Fengshou Liu; Qing Wu

doi:10.1021/om300380b

Substituent Effects of the Backbone in α-Diimine Palladium Catalysts on Homo- and Copolymerization of Ethylene with Methyl Acrylate

Organometallics ◽

10.1021/om300380b ◽

2012 ◽

Vol 31 (17) ◽

pp. 6054-6062 ◽

Cited By ~ 104

Author(s):

Lihua Guo ◽

Haiyang Gao ◽

Qirui Guan ◽

Haibin Hu ◽

Juean Deng ◽

...

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Substituent Effects

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The leaching and re-deposition of metal species from and onto conventional supported palladium catalysts in the Heck reaction of iodobenzene and methyl acrylate in N-methylpyrrolidone

Journal of Molecular Catalysis A Chemical ◽

10.1016/s1381-1169(01)00436-8 ◽

2002 ◽

Vol 180 (1-2) ◽

pp. 211-219 ◽

Cited By ~ 134

Author(s):

Fengyu Zhao ◽

Masayuki Shirai ◽

Yutaka Ikushima ◽

Masahiko Arai

Keyword(s):

Methyl Acrylate ◽

Heck Reaction ◽

Palladium Catalysts ◽

Metal Species ◽

Supported Palladium Catalysts ◽

Supported Palladium

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Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using “Sandwich” Diimine Palladium Catalysts

ACS Catalysis ◽

10.1021/cs5016029 ◽

2014 ◽

Vol 5 (1) ◽

pp. 456-464 ◽

Cited By ~ 100

Author(s):

Kate E. Allen ◽

Jesús Campos ◽

Olafs Daugulis ◽

Maurice Brookhart

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Living Polymerization ◽

Ethylene Methyl Acrylate

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Copper-Free Monomeric and Dendritic Palladium Catalysts for the Sonogashira Reaction: Substituent Effects, Synthetic Applications, and the Recovery and Re-Use of the Catalysts

Chemistry - A European Journal ◽

10.1002/chem.200400150 ◽

2004 ◽

Vol 10 (16) ◽

pp. 3936-3944 ◽

Cited By ~ 86

Author(s):

Karine Heuzé ◽

Denise Méry ◽

Dominique Gauss ◽

Jean-Claude Blais ◽

Didier Astruc

Keyword(s):

Palladium Catalysts ◽

Substituent Effects ◽

Sonogashira Reaction

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Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts

Chemical Science ◽

10.1039/c5sc03361f ◽

2016 ◽

Vol 7 (1) ◽

pp. 737-744 ◽

Cited By ~ 43

Author(s):

Yusuke Mitsushige ◽

Brad P. Carrow ◽

Shingo Ito ◽

Kyoko Nozaki

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Ethylene Methyl Acrylate

A new series of palladium catalysts ligated by a chelating bisphosphine monoxide bearing diarylphosphino groups (aryl-BPMO) exhibits markedly higher reactivity for ethylene/methyl acrylate copolymerisation.

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Copolymerization of ethylene and methyl acrylate by palladium catalysts bearing IzQO ligands containing methoxyethyl ether moieties and salt effects for polymerization

Polymer Journal ◽

10.1038/s41428-021-00500-3 ◽

2021 ◽

Author(s):

Shumpei Akita ◽

Kyoko Nozaki

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Salt Effects

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Effects of chemical modification of supports on properties of tertiary amino resin dispersed palladium catalysts for the hydrogenation of methyl acrylate

Makromolekulare Chemie Macromolecular Symposia ◽

10.1002/masy.19920590110 ◽

1992 ◽

Vol 59 (1) ◽

pp. 99-111

Author(s):

Chunfu Chen ◽

Juntan Sun ◽

Hong Li ◽

Binglin He

Keyword(s):

Chemical Modification ◽

Methyl Acrylate ◽

Palladium Catalysts ◽

Amino Resin ◽

Tertiary Amino

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Heck Reactions of Iodobenzene and Methyl Acrylate with Conventional Supported Palladium Catalysts in the Presence of Organic and/or Inorganic Bases without Ligands

Chemistry - A European Journal ◽

10.1002/(sici)1521-3765(20000303)6:5<843::aid-chem843>3.0.co;2-g ◽

2000 ◽

Vol 6 (5) ◽

pp. 843-848 ◽

Cited By ~ 223

Author(s):

Fengyu Zhao ◽

Bhalchandra M. Bhanage ◽

Masayuki Shirai ◽

Masahiko Arai

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Heck Reactions ◽

Supported Palladium Catalysts ◽

Supported Palladium

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Efficient ethylene copolymerization with polar monomers using palladium anilinonaphthoquinone catalysts

Polymer Chemistry ◽

10.1039/c8py01292j ◽

2018 ◽

Vol 9 (45) ◽

pp. 5476-5482 ◽

Cited By ~ 9

Author(s):

Lin Ding ◽

Hailong Cheng ◽

Yanqing Li ◽

Ryo Tanaka ◽

Takeshi Shiono ◽

...

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Polar Monomers

Copolymerizations of ethylene with methyl acrylate (MA) and 5-norbornen-2-yl acetate (NBAC) were explored using anilinonaphthoquinone-ligated palladium catalysts.

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Copolymerization of Ethylene and Methyl Acrylate by Cationic Palladium Catalysts That Contain Phosphine-Diethyl Phosphonate Ancillary Ligands

Organometallics ◽

10.1021/om5004489 ◽

2014 ◽

Vol 33 (13) ◽

pp. 3546-3555 ◽

Cited By ~ 61

Author(s):

Nathan D. Contrella ◽

Jessica R. Sampson ◽

Richard F. Jordan

Keyword(s):

Methyl Acrylate ◽

Palladium Catalysts ◽

Ancillary Ligands ◽

Cationic Palladium

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Amine–imine palladium catalysts for living polymerization of ethylene and copolymerization of ethylene with methyl acrylate: incorporation of acrylate units into the main chain and branch end

Polymer Chemistry ◽

10.1039/c5py01743b ◽

2016 ◽

Vol 7 (3) ◽

pp. 529-537 ◽

Cited By ~ 34

Author(s):

Haibin Hu ◽

Darui Chen ◽

Haiyang Gao ◽

Liu Zhong ◽

Qing Wu

Keyword(s):

Methyl Acrylate ◽

Palladium Catalyst ◽

Palladium Catalysts ◽

Main Chain ◽

Living Polymerization ◽

Branched Copolymers

A bulky amine–imine palladium catalyst can polymerize ethylene in a living fashion. Copolymerizations of ethylene and methyl acrylate afford branched copolymers with terminal and main chain acrylate units.

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