scholarly journals Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts

2016 ◽  
Vol 7 (1) ◽  
pp. 737-744 ◽  
Author(s):  
Yusuke Mitsushige ◽  
Brad P. Carrow ◽  
Shingo Ito ◽  
Kyoko Nozaki

A new series of palladium catalysts ligated by a chelating bisphosphine monoxide bearing diarylphosphino groups (aryl-BPMO) exhibits markedly higher reactivity for ethylene/methyl acrylate copolymerisation.

2017 ◽  
Vol 144 ◽  
pp. 401-410 ◽  
Author(s):  
Florian Cavodeau ◽  
Amandine Viretto ◽  
Belkacem Otazaghine ◽  
José-Marie Lopez-Cuesta ◽  
Christelle Delaite

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