Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using “Sandwich” Diimine Palladium Catalysts

ACS Catalysis ◽  
2014 ◽  
Vol 5 (1) ◽  
pp. 456-464 ◽  
Author(s):  
Kate E. Allen ◽  
Jesús Campos ◽  
Olafs Daugulis ◽  
Maurice Brookhart
Keyword(s):  
Methyl Acrylate ◽  
Palladium Catalysts ◽  
Living Polymerization ◽  
Ethylene Methyl Acrylate

scholarly journals Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts

2016 ◽  
Vol 7 (1) ◽  
pp. 737-744 ◽  
Author(s):  
Yusuke Mitsushige ◽  
Brad P. Carrow ◽  
Shingo Ito ◽  
Kyoko Nozaki
Keyword(s):  
Methyl Acrylate ◽  
Palladium Catalysts ◽  
Ethylene Methyl Acrylate

A new series of palladium catalysts ligated by a chelating bisphosphine monoxide bearing diarylphosphino groups (aryl-BPMO) exhibits markedly higher reactivity for ethylene/methyl acrylate copolymerisation.

Amine–imine palladium catalysts for living polymerization of ethylene and copolymerization of ethylene with methyl acrylate: incorporation of acrylate units into the main chain and branch end

2016 ◽  
Vol 7 (3) ◽  
pp. 529-537 ◽  
Author(s):  
Haibin Hu ◽  
Darui Chen ◽  
Haiyang Gao ◽  
Liu Zhong ◽  
Qing Wu
Keyword(s):  
Methyl Acrylate ◽  
Palladium Catalyst ◽  
Palladium Catalysts ◽  
Main Chain ◽  
Living Polymerization ◽  
Branched Copolymers

A bulky amine–imine palladium catalyst can polymerize ethylene in a living fashion. Copolymerizations of ethylene and methyl acrylate afford branched copolymers with terminal and main chain acrylate units.

scholarly journals Influence of colemanite on the fire retardancy of ethylene-vinyl acetate and ethylene-methyl acrylate copolymers

2017 ◽  
Vol 144 ◽  
pp. 401-410 ◽  
Author(s):  
Florian Cavodeau ◽  
Amandine Viretto ◽  
Belkacem Otazaghine ◽  
José-Marie Lopez-Cuesta ◽  
Christelle Delaite
Keyword(s):  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Ethylene Vinyl Acetate ◽  
Fire Retardancy ◽  
Ethylene Methyl Acrylate
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