One-dimensional organometallic material. 1. Synthesis and spectroscopic characterization of linear mono-, bi-, and trimetallic bis(methyldiphenylphosphine)nickel complexes having 1,4-tetrafluorophenylene bridges

1992 ◽  
Vol 11 (2) ◽  
pp. 893-900 ◽  
Author(s):  
Robert McDonald ◽  
K. Craig Sturge ◽  
Allen D. Hunter ◽  
Lonni Shilliday
CrystEngComm ◽  
2018 ◽  
Vol 20 (13) ◽  
pp. 1783-1796 ◽  
Author(s):  
Bahram Ghanbari ◽  
Leila Shahhoseini ◽  
Agata Owczarzak ◽  
Maciej Kubicki ◽  
Reza Kia ◽  
...  

A new series of coordination polymers capable of adsorbing anions have been synthesized by employing a dipyridine substituted diazacrown macrocycle as linker.


1985 ◽  
Vol 17 (12) ◽  
pp. 1253-1261 ◽  
Author(s):  
Masahiko Sisido ◽  
Akira Okamoto ◽  
Syun Egusa ◽  
Yukio Imanishi

2003 ◽  
Vol 58 (11) ◽  
pp. 1045-1054 ◽  
Author(s):  
Theocharis C. Stamatatos ◽  
Eugenia Katsoulakoua ◽  
Vassilios Nastopoulos ◽  
Catherine P. Raptopoulou ◽  
Evy Manessi-Zoupa ◽  
...  

Compound [Cd(O2CMe)(O2CPh)(H2O)2]n (1) was initially obtained in a serendipitous way during efforts to prepare a CdII /PhCO2 −/bepy complex (bepy = 2-benzoylpyridine). With the identity of 1 established by single-crystal X-ray crystallography, a rational preparative route to this complex was designed and carried out by reacting Cd(O2CMe)2·2H2O with a slight excess of PhCOOH in MeCN under reflux. The crystal structure of 1 consists of isolated zig-zag chains. The CdII atom is coordinated to five carboxylate and two aqua oxygen atoms creating a distorted, capped trigonal prismatic coordination polyhedron. The acetate group exhibits the η1:η2:μ2 coordination mode, while the benzoate ligand is chelating. There is an extensive hydrogen-bonding network which reinforces the chains and also links them generating sheets. The new complex was characterized by IR, far-IR, Raman, CP MAS and solution 113Cd NMR spectroscopy. The spectroscopic data are discussed in terms of the nature of bonding and the known structure. An anhydrous compound with the empirical formula Cd(O2CMe)(O2CPh) was isolated during the thermal decomposition of 1; the vibrational study of this thermally stable intermediate supports an 1D polymeric structure with 6-coordinate CdII ions.


2001 ◽  
Vol 74 (6) ◽  
pp. 794 ◽  
Author(s):  
Antoine Royant ◽  
Karl Edman ◽  
Thomas Ursby ◽  
Eva Pebay-Peyroula ◽  
Ehud. M. Landau ◽  
...  

Author(s):  
Kazuyuki MIYAKITA ◽  
Keisuke NAKANO ◽  
Masakazu SENGOKU ◽  
Shoji SHINODA

Sign in / Sign up

Export Citation Format

Share Document