Preparation and Spectroscopic Characterization of [Pt(en)2I2][Pt(CN)4]:  A New Quasi-One-Dimensional Mixed Valence Chain Material in a Completely Ordered Lattice

1999 ◽  
Vol 103 (48) ◽  
pp. 10566-10571 ◽  
Author(s):  
James A. Brozik ◽  
Brian L. Scott ◽  
Basil I. Swanson
Keyword(s):  
Mixed Valence ◽  
Spectroscopic Characterization ◽  
One Dimensional

Synthesis, X-ray crystallography, thermogravimetric analysis and spectroscopic characterization of isostructural one-dimensional coordination polymers as sorbents for some anions

CrystEngComm ◽  
2018 ◽  
Vol 20 (13) ◽  
pp. 1783-1796 ◽  
Author(s):  
Bahram Ghanbari ◽  
Leila Shahhoseini ◽  
Agata Owczarzak ◽  
Maciej Kubicki ◽  
Reza Kia ◽  
...  
Keyword(s):  
Thermogravimetric Analysis ◽  
Coordination Polymers ◽  
Spectroscopic Characterization ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography

A new series of coordination polymers capable of adsorbing anions have been synthesized by employing a dipyridine substituted diazacrown macrocycle as linker.

scholarly journals One-Dimensional Aromatic Crystals in Solution VI. Synthesis and Spectroscopic Characterization of Poly(β-9-anthrylmethyl L-aspartate)

1985 ◽  
Vol 17 (12) ◽  
pp. 1253-1261 ◽  
Author(s):  
Masahiko Sisido ◽  
Akira Okamoto ◽  
Syun Egusa ◽  
Yukio Imanishi
Keyword(s):  
Spectroscopic Characterization ◽  
One Dimensional

Cadmium Carboxylate Chemistry: Preparation, Crystal Structure, and Thermal and Spectroscopic Characterization of the One-dimensional Polymer [Cd(O2CMe)(O2CPh)(H2O)2]n

2003 ◽  
Vol 58 (11) ◽  
pp. 1045-1054 ◽  
Author(s):  
Theocharis C. Stamatatos ◽  
Eugenia Katsoulakoua ◽  
Vassilios Nastopoulos ◽  
Catherine P. Raptopoulou ◽  
Evy Manessi-Zoupa ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Spectroscopic Characterization ◽  
One Dimensional ◽  
X Ray Crystallography ◽  
Anhydrous Compound ◽  
Trigonal Prismatic Coordination ◽  
The One ◽  
Trigonal Prismatic ◽  
Preparative Route

Compound [Cd(O2CMe)(O2CPh)(H2O)2]n (1) was initially obtained in a serendipitous way during efforts to prepare a CdII /PhCO2 −/bepy complex (bepy = 2-benzoylpyridine). With the identity of 1 established by single-crystal X-ray crystallography, a rational preparative route to this complex was designed and carried out by reacting Cd(O2CMe)2·2H2O with a slight excess of PhCOOH in MeCN under reflux. The crystal structure of 1 consists of isolated zig-zag chains. The CdII atom is coordinated to five carboxylate and two aqua oxygen atoms creating a distorted, capped trigonal prismatic coordination polyhedron. The acetate group exhibits the η1:η2:μ2 coordination mode, while the benzoate ligand is chelating. There is an extensive hydrogen-bonding network which reinforces the chains and also links them generating sheets. The new complex was characterized by IR, far-IR, Raman, CP MAS and solution 113Cd NMR spectroscopy. The spectroscopic data are discussed in terms of the nature of bonding and the known structure. An anhydrous compound with the empirical formula Cd(O2CMe)(O2CPh) was isolated during the thermal decomposition of 1; the vibrational study of this thermally stable intermediate supports an 1D polymeric structure with 6-coordinate CdII ions.

A new one-dimensional mixed-valence copper polymer: the synthesis and characterization of [Cu3Br4(DMF)2(H2O)]n

Polyhedron ◽  
1994 ◽  
Vol 13 (19) ◽  
pp. 2793-2796 ◽  
Author(s):  
Alexander J. Blake ◽  
Rowenna L. Dorse ◽  
Jeremy M. Rawson ◽  
Richard E.P. Winpenny
Keyword(s):  
Mixed Valence ◽  
Synthesis And Characterization ◽  
One Dimensional ◽  
Copper Polymer
Sign in / Sign up

Export Citation Format

Share Document