Selective Oxidation of a Single Primary Alcohol Function in Oligopyridine Frameworks

2004 ◽  
Vol 6 (17) ◽  
pp. 2865-2868 ◽  
Author(s):  
Raymond Ziessel ◽  
Patrick Nguyen ◽  
Laurent Douce ◽  
Michèle Cesario ◽  
Claude Estournes
Keyword(s):  
Selective Oxidation ◽  
Primary Alcohol

scholarly journals Convergent synthesis of the tetrasaccharide repeating unit of theO-antigen ofShigella boydiitype 9

2011 ◽  
Vol 7 ◽  
pp. 1182-1188
Author(s):  
Abhishek Santra ◽  
Anup Kumar Misra
Keyword(s):  
Functional Groups ◽  
Selective Oxidation ◽  
Primary Alcohol ◽  
High Yield ◽  
Carboxylic Group ◽  
Convergent Synthesis ◽  
Shigella Boydii ◽  
Excellent Yield ◽  
Convenient Synthesis

A convenient synthesis of the tetrasaccharide repeating unit of theO-antigen ofShigella boydiitype 9 has been achieved in excellent yield using a [2 + 2] block glycosylation strategy. TEMPO-mediated selective oxidation of the primary alcohol of the tetrasaccharide derivative8to the carboxylic group followed by deprotection of the functional groups furnished target tetrasaccharide1as its 4-methoxyphenyl glycoside in high yield.

Optimization of conditions for 2,2,6,6-tetramethyl-1-piperidinyl oxoammonium ion/sodium hypochlorite-catalyzed selective oxidation of the primary alcohol in 1-Monolaurin

2013 ◽  
Vol 22 (3) ◽  
pp. 621-629
Author(s):  
Seon Min Ahn ◽  
Kyung Min Park ◽  
Seung Jun Choi ◽  
Seokwon Lim ◽  
Dong-Hyun Kang ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Sodium Hypochlorite ◽  
Primary Alcohol

Preparation of catalyst precursors for selective oxidation of n-butane by exfoliation–reduction of VOPO4·2H2O in primary alcohol

2003 ◽  
Vol 78 (1-4) ◽  
pp. 281-290 ◽  
Author(s):  
Yuichi Kamiya ◽  
Satoshi Ueki ◽  
Norihito Hiyoshi ◽  
Naoki Yamamoto ◽  
Toshio Okuhara
Keyword(s):  
Selective Oxidation ◽  
Primary Alcohol

A New Synthesis of an Important Prostaglandin Intermediate by Selective Oxidation of a Trimethylsilylated Primary Alcohol to the Corresponding Aldehyde

Synthesis ◽  
1987 ◽  
Vol 1987 (11) ◽  
pp. 1012-1013 ◽  
Author(s):  
Rainer Mahrwald ◽  
Fritz Theil ◽  
Hans Schick ◽  
Hans-Joachim Palme ◽  
Heidrun Nowak ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Primary Alcohol ◽  
New Synthesis

Selective Oxidation of Glycerol with O2 Catalyzed by Fluorine-Modified CuNiAl Hydrotalcite

2013 ◽  
Vol 800 ◽  
pp. 424-427
Author(s):  
Gong De Wu ◽  
Xiao Li Wang ◽  
Xian Feng Liu ◽  
Xiao Tian Zhang
Keyword(s):  
Heterogeneous Catalyst ◽  
Selective Oxidation ◽  
Main Product ◽  
Primary Alcohol ◽  
Glyceric Acid ◽  
Layer Structures ◽  
Fluorine Anion ◽  
Oxygenated Products

A fluorine anion modified CuNiAl hydrotalcite (CuNiAl-LDH (F-)) was prepared for the selective oxidation of glycerol (GLY) using O2 as oxidant. It was found that the obtained catalyst with typical layer structures of hydrotalcite compounds was an effective heterogeneous catalyst in GLY oxidation. Under the present conditions, the main product was the C3 oxygenated products of primary alcohol glyceric acid (GLYAC). The highest conversion of GLY reached 32.0% with 58.1% of the selectivity to GLYAC.

Selective oxidation of aniline into azoxybenzene catalyzed by Nb-peroxo@iron oxides at room temperature

2020 ◽  
Vol 44 (21) ◽  
pp. 8710-8717
Author(s):  
André L. D. Lima ◽  
Humberto V. Fajardo ◽  
André E. Nogueira ◽  
Márcio C. Pereira ◽  
Luiz C. A. Oliveira ◽  
...  
Keyword(s):  
Iron Oxides ◽  
Selective Oxidation ◽  
Room Temperature ◽  
High Selectivity

Nb-peroxo@iron oxides show high selectivity and activity in aniline conversion to azoxybenzene.

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