Prevalence of Anisotropic Shell Growth in Rare Earth Core–Shell Upconversion Nanocrystals

ACS Nano ◽  
2013 ◽  
Vol 7 (5) ◽  
pp. 4393-4402 ◽  
Author(s):  
Chao Zhang ◽  
Jim Yang Lee
RSC Advances ◽  
2016 ◽  
Vol 6 (12) ◽  
pp. 9612-9618 ◽  
Author(s):  
Ming Chen ◽  
Jia-Hong Wang ◽  
Zhi-Jun Luo ◽  
Zi-Qiang Cheng ◽  
Ya-Fang Zhang ◽  
...  

The synthesis of metal/rare-earth core/shell hetero-nanostructures through directly coating rare-earth compound onto the surface of Au nanocrystals.


2021 ◽  
Vol 19 (1) ◽  
Author(s):  
Zhuxin Wei ◽  
Guangxin Duan ◽  
Baoxing Huang ◽  
Shanshan Qiu ◽  
Dandan Zhou ◽  
...  

Abstract Background Fluorescence imaging as the beacon for optical navigation has wildly developed in preclinical studies due to its prominent advantages, including noninvasiveness and superior temporal resolution. However, the traditional optical methods based on ultraviolet (UV, 200–400 nm) and visible light (Vis, 400–650 nm) limited by their low penetration, signal-to-noise ratio, and high background auto-fluorescence interference. Therefore, the development of near-infrared-II (NIR-II 1000–1700 nm) nanoprobe attracted significant attentions toward in vivo imaging. Regrettably, most of the NIR-II fluorescence probes, especially for inorganic NPs, were hardly excreted from the reticuloendothelial system (RES), yielding the anonymous long-term circulatory safety issue. Results Here, we develop a facile strategy for the fabrication of Nd3+-doped rare-earth core–shell nanoparticles (Nd-RENPs), NaGdF4:5%Nd@NaLuF4, with strong emission in the NIR-II window. What’s more, the Nd-RENPs could be quickly eliminated from the hepatobiliary pathway, reducing the potential risk with the long-term retention in the RES. Further, the Nd-RENPs are successfully utilized for NIR-II in vivo imaging and magnetic resonance imaging (MRI) contrast agents, enabling the precise detection of breast cancer. Conclusions The rationally designed Nd-RENPs nanoprobes manifest rapid-clearance property revealing the potential application toward the noninvasive preoperative imaging of tumor lesions and real-time intra-operative supervision. Graphical abstract


2015 ◽  
Vol 87 (11) ◽  
pp. 5745-5752 ◽  
Author(s):  
Lei Chen ◽  
Xiaomin Li ◽  
Dengke Shen ◽  
Lei Zhou ◽  
Dan Zhu ◽  
...  
Keyword(s):  

2021 ◽  
Author(s):  
Zhuxin Wei ◽  
Guangxin Duan ◽  
Baoxing Huang ◽  
Shanshan Qiu ◽  
Dandan Zhou ◽  
...  

Abstract BackgroundFluorescence imaging as the beacon for optical navigation has wildly developed in preclinical studies due to its prominent advantages, including noninvasiveness and superior temporal resolution. However, the traditional optical methods based on ultraviolet (UV, 200-400 nm) and visible light (Vis, 400-650 nm) limited by their low penetration, signal-to-noise ratio, and high background auto-fluorescence interference. Therefore, the development of near-infrared-II (NIR-II 1000-1700 nm) nanoprobe attracted significant attentions toward in vivo imaging. Regrettably, most of the NIR-II fluorescence probes, especially for inorganic NPs, were hardly excreted from the reticuloendothelial system (RES), yielding the anonymous long-term circulatory safety issue. ResultsHere, we develop a facile strategy for the fabrication of Nd3+-doped rare-earth core-shell nanoparticles (Nd-RENPs), NaGdF4:5%Nd@NaLuF4, with strong emission in the NIR-II window. What’s more, the Nd-RENPs could be quickly eliminated from the hepatobiliary pathway, reducing the potential risk with the long-term retention in the RES. Further, the Nd-RENPs are successfully utilized for NIR-II in vivo imaging and magnetic resonance imaging (MRI) contrast agents, enabling the precise detection of breast cancer. ConclusionsThe rational designed Nd-RENPs nanoprobes manifest rapid-clearance property revealing the potential application toward the noninvasive preoperative imaging of tumor lesions and real-time intra-operative supervision.


Author(s):  
Jiajia Ning ◽  
Yuan Xiong ◽  
Stephen V. Kershaw ◽  
Andrey L. Rogach

2017 ◽  
Vol 27 (36) ◽  
pp. 1701842 ◽  
Author(s):  
Fengwen Kang ◽  
Jijun He ◽  
Tianying Sun ◽  
Zhi Yong Bao ◽  
Feng Wang ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (101) ◽  
pp. 83149-83154 ◽  
Author(s):  
Di Kang ◽  
Xiaoyan Song ◽  
Jinfeng Xing

Rare-earth upconversion nanoparticles (UCNPs) with α and β phases were prepared. UCNPs with core–shell structure were prepared and modified to be hydrophilic by ligand-free hydrophilic modification.


Nanoscale ◽  
2021 ◽  
Author(s):  
Rui Shi ◽  
Carlos D S Brites ◽  
Luis Antonio Dias Carlos

The hexagonal-phase (β) of NaREF4 upconversion nanocrystals (RE = rare earth elements) has been widely employed because of the outstanding luminescence performance, yet less is known about the essence of...


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