Preferential Adsorption of Horse Heart Cytochromecon Nanometer-Scale Domains of a Phase-Separated Binary Self-Assembled Monolayer of 3-Mercaptopropionic Acid and 1-Hexadecanethiol on Au(111)

Nano Letters ◽  
2002 ◽  
Vol 2 (9) ◽  
pp. 1021-1025 ◽  
Author(s):  
Daisuke Hobara ◽  
Shin-ichiro Imabayashi ◽  
Takashi Kakiuchi
1998 ◽  
Vol 73 (14) ◽  
pp. 1976-1978 ◽  
Author(s):  
A. Inoue ◽  
T. Ishida ◽  
N. Choi ◽  
W. Mizutani ◽  
H. Tokumoto

2007 ◽  
Vol 19 (13) ◽  
pp. 1415-1420 ◽  
Author(s):  
Valber A. Pedrosa ◽  
Josiane Caetano ◽  
Sergio A. S. Machado ◽  
Renato S. Freire ◽  
Mauro Bertotti

2013 ◽  
Vol 4 ◽  
pp. 638-648 ◽  
Author(s):  
Tatjana Ladnorg ◽  
Alexander Welle ◽  
Stefan Heißler ◽  
Christof Wöll ◽  
Hartmut Gliemann

Surface anchored metal-organic frameworks, SURMOFs, are highly porous materials, which can be grown on modified substrates as highly oriented, crystalline coatings by a quasi-epitaxial layer-by-layer method (liquid-phase epitaxy, or LPE). The chemical termination of the supporting substrate is crucial, because the most convenient method for substrate modification is the formation of a suitable self-assembled monolayer. The choice of a particular SAM also allows for control over the orientation of the SURMOF. Here, we demonstrate for the first time the site-selective growth of the SURMOF HKUST-1 on thiol-based self-assembled monolayers patterned by the nanografting technique, with an atomic force microscope as a structuring tool. Two different approaches were applied: The first one is based on 3-mercaptopropionic acid molecules which are grafted in a 1-decanethiolate SAM, which serves as a matrix for this nanolithography. The second approach uses 16-mercaptohexadecanoic acid, which is grafted in a matrix of an 1-octadecanethiolate SAM. In both cases a site-selective growth of the SURMOF is observed. In the latter case the roughness of the HKUST-1 is found to be significantly higher than for the 1-mercaptopropionic acid. The successful grafting process was verified by time-of-flight secondary ion mass spectrometry and atomic force microscopy. The SURMOF structures grown via LPE were investigated and characterized by atomic force microscopy and Fourier-transform infrared microscopy.


2012 ◽  
Vol 161 (1) ◽  
pp. 322-328 ◽  
Author(s):  
Min Sun ◽  
Bin Ding ◽  
Jianyong Yu ◽  
You-Lo Hsieh ◽  
Gang Sun

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