Controlled/Living Cationic Polymerization ofp-Methoxystyrene in Solution and Aqueous Dispersion Using Tris(pentafluorophenyl)borane as a Lewis Acid:  Acetonitrile Does the Job†

2007 ◽  
Vol 40 (3) ◽  
pp. 482-490 ◽  
Author(s):  
Sergei V. Kostjuk ◽  
Alexei V. Radchenko ◽  
François Ganachaud
Keyword(s):  
Lewis Acid ◽  
Cationic Polymerization ◽  
Aqueous Dispersion ◽  
Living Cationic Polymerization

Living Cationic Polymerization of Styrene with TiCl3(OiPr) as a Lewis Acid Activator1

1996 ◽  
Vol 29 (19) ◽  
pp. 6100-6103 ◽  
Author(s):  
Toshiyuki Hasebe ◽  
Masami Kamigaito ◽  
Mitsuo Sawamoto
Keyword(s):  
Lewis Acid ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization

Metal-Free Living Cationic Polymerization Using Diaryliodonium Salts as Organic Lewis Acid Catalysts

2020 ◽  
Vol 53 (11) ◽  
pp. 4185-4192
Author(s):  
Rui Haraguchi ◽  
Tsuyoshi Nishikawa ◽  
Arihiro Kanazawa ◽  
Sadahito Aoshima
Keyword(s):  
Lewis Acid ◽  
Cationic Polymerization ◽  
Acid Catalysts ◽  
Lewis Acid Catalysts ◽  
Free Living ◽  
Metal Free ◽  
Living Cationic Polymerization ◽  
Diaryliodonium Salts

scholarly journals A well-defined block copolymer synthesis via living cationic polymerization and nitroxide-mediated polymerization using carboxylic acid-based alkoxyamines as a dual initiator

2016 ◽  
Vol 7 (8) ◽  
pp. 1659-1667 ◽  
Author(s):  
Dao Le ◽  
Trang N. T. Phan ◽  
Laurent Autissier ◽  
Laurence Charles ◽  
Didier Gigmes
Keyword(s):  
Carboxylic Acid ◽  
Block Copolymer ◽  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization ◽  
Nitroxide Mediated Polymerization ◽  
Protonic Acids

A series of carboxylic acid-based alkoxyamines associated with SnBr4, a Lewis acid, have been used as protonic acids of a binary initiating system to control the cationic polymerization of vinyl ether.

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