A well-defined block copolymer synthesis via living cationic polymerization and nitroxide-mediated polymerization using carboxylic acid-based alkoxyamines as a dual initiator

Dao Le; Trang N. T. Phan; Laurent Autissier; Laurence Charles; Didier Gigmes

doi:10.1039/c5py01934f

A well-defined block copolymer synthesis via living cationic polymerization and nitroxide-mediated polymerization using carboxylic acid-based alkoxyamines as a dual initiator

Polymer Chemistry ◽

10.1039/c5py01934f ◽

2016 ◽

Vol 7 (8) ◽

pp. 1659-1667 ◽

Cited By ~ 17

Author(s):

Dao Le ◽

Trang N. T. Phan ◽

Laurent Autissier ◽

Laurence Charles ◽

Didier Gigmes

Keyword(s):

Carboxylic Acid ◽

Block Copolymer ◽

Vinyl Ether ◽

Lewis Acid ◽

Cationic Polymerization ◽

Living Cationic Polymerization ◽

Nitroxide Mediated Polymerization ◽

Protonic Acids

A series of carboxylic acid-based alkoxyamines associated with SnBr4, a Lewis acid, have been used as protonic acids of a binary initiating system to control the cationic polymerization of vinyl ether.

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Living cationic polymerization of vinyl ethers with carboxylic acid/tin tetrahalide initiating systems. I. New initiating systems based on acetic acid and selection of Lewis acid and basic additive leading to living polymers with low polydispersity

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/(sici)1099-0518(199812)36:17<3173::aid-pola20>3.0.co;2-q ◽

1998 ◽

Vol 36 (17) ◽

pp. 3173-3185 ◽

Cited By ~ 24

Author(s):

Tamotsu Hashimoto ◽

Toshiaki Iwata ◽

Atsushi Minami ◽

Toshiyuki Kodaira

Keyword(s):

Acetic Acid ◽

Carboxylic Acid ◽

Lewis Acid ◽

Cationic Polymerization ◽

Vinyl Ethers ◽

Living Cationic Polymerization ◽

Basic Additive ◽

Living Polymers ◽

Selection Of

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Living Coupling Reaction in Living Cationic Polymerization. 2. Synthesis and Characterization of Amphiphilic A2B2Star−Block Copolymer: Poly[bis(isobutylene)-star-bis(methyl vinyl ether)]

Macromolecules ◽

10.1021/ma971715y ◽

1998 ◽

Vol 31 (8) ◽

pp. 2480-2487 ◽

Cited By ~ 50

Author(s):

Young Cheol Bae ◽

Rudolf Faust

Keyword(s):

Block Copolymer ◽

Vinyl Ether ◽

Cationic Polymerization ◽

Coupling Reaction ◽

Synthesis And Characterization ◽

Methyl Vinyl ◽

Living Cationic Polymerization ◽

Copolymer Poly ◽

Methyl Vinyl Ether

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Living cationic polymerization of vinyl ethers with carboxylic acid/tin tetrahalide initiating systems. III. Benzoic acid and related weakly acidic carboxylic acids for the living polymerization of isobutyl vinyl ether

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/(sici)1099-0518(20000215)38:4<781::aid-pola14>3.0.co;2-v ◽

2000 ◽

Vol 38 (4) ◽

pp. 781-784 ◽

Cited By ~ 11

Author(s):

Tamotsu Hashimoto ◽

Toshitaka Takahashi ◽

Toshiyuki Kodaira

Keyword(s):

Carboxylic Acid ◽

Benzoic Acid ◽

Carboxylic Acids ◽

Vinyl Ether ◽

Cationic Polymerization ◽

Living Polymerization ◽

Vinyl Ethers ◽

Living Cationic Polymerization

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Living cationic polymerization of vinyl ethers by electrophile/lewis acid initiating systems. VII. Living cationic polymerization of isobutyl vinyl ether by trimethylsilyl halide/zinc halide initiating systems in the presence of p-methoxybenzaldehyde: Effects of halide anions and zinc halides

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.1991.080291310 ◽

1991 ◽

Vol 29 (13) ◽

pp. 1909-1915 ◽

Cited By ~ 9

Author(s):

Masami Kamigaito ◽

Mitsuo Sawamoto ◽

Toshinobu Higashimura

Keyword(s):

Vinyl Ether ◽

Lewis Acid ◽

Cationic Polymerization ◽

Vinyl Ethers ◽

Living Cationic Polymerization ◽

Halide Anions

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Living cationic polymerization of isobutyl vinyl ether by hydrogen iodide/Lewis acid initiating systems: effects of Lewis acid activators and polymerization kinetics

Macromolecules ◽

10.1021/ma00194a008 ◽

1989 ◽

Vol 22 (4) ◽

pp. 1552-1557 ◽

Cited By ~ 63

Author(s):

Kazushige Kojima ◽

Mitsuo Sawamoto ◽

Toshinobu Higashimura

Keyword(s):

Vinyl Ether ◽

Lewis Acid ◽

Cationic Polymerization ◽

Polymerization Kinetics ◽

Hydrogen Iodide ◽

Living Cationic Polymerization

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Living cationic polymerization of isobutyl vinyl ether by RCOOH/Lewis acid initiating systems: effects of carboxylate ions and Lewis acid activators

Macromolecules ◽

10.1021/ma00014a003 ◽

1991 ◽

Vol 24 (14) ◽

pp. 3988-3992 ◽

Cited By ~ 58

Author(s):

Masami Kamigaito ◽

Mitsuo Sawamoto ◽

Toshinobu Higashimura

Keyword(s):

Vinyl Ether ◽

Lewis Acid ◽

Cationic Polymerization ◽

Living Cationic Polymerization

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Living cationic polymerization of isobutyl vinyl ether by hydrogen chloride/Lewis acid initiating systems in the presence of salts: in-situ direct NMR analysis of the growing species

Macromolecules ◽

10.1021/ma00059a023 ◽

1993 ◽

Vol 26 (7) ◽

pp. 1643-1649 ◽

Cited By ~ 87

Author(s):

Masami Kamigaito ◽

Yoshihiro Maeda ◽

Mitsuo Sawamoto ◽

Toshinobu Higashimura

Keyword(s):

Hydrogen Chloride ◽

Vinyl Ether ◽

Lewis Acid ◽

Cationic Polymerization ◽

Nmr Analysis ◽

Living Cationic Polymerization

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Alkoxy-Substituted Titanium(IV) Chlorides as Lewis Acid Activators for Living Cationic Polymerization of Isobutyl Vinyl Ether: Control of Lewis Acidity in the Design of Initiating Systems

Macromolecules ◽

10.1021/ma00120a037 ◽

1995 ◽

Vol 28 (16) ◽

pp. 5671-5675 ◽

Cited By ~ 16

Author(s):

Masami Kamigaito ◽

Mitsuo Sawamoto ◽

Toshinobu Higashimura

Keyword(s):

Vinyl Ether ◽

Lewis Acid ◽

Cationic Polymerization ◽

Lewis Acidity ◽

Living Cationic Polymerization

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Lewis acid-specific polymerization behaviors in living cationic polymerization of vinyl ether with a malonate group

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.26088 ◽

2012 ◽

Vol 50 (15) ◽

pp. 2993-2998 ◽

Cited By ~ 8

Author(s):

Yukari Oda ◽

Tomohiro Tsujino ◽

Shokyoku Kanaoka ◽

Sadahito Aoshima

Keyword(s):

Vinyl Ether ◽

Lewis Acid ◽

Cationic Polymerization ◽

Living Cationic Polymerization

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Design of Benign Initiator for Living Cationic Polymerization of Vinyl Ethers: Facile in Situ Generation of Vinyl Ether–Hydrogen Halide Adducts and Subsequent Controlled Polymerization without a Lewis Acid Catalyst

Macromolecules ◽

10.1021/ma402490f ◽

2014 ◽

Vol 47 (5) ◽

pp. 1578-1585 ◽

Cited By ~ 26

Author(s):

Arihiro Kanazawa ◽

Ryo Hashizume ◽

Shokyoku Kanaoka ◽

Sadahito Aoshima

Keyword(s):

Vinyl Ether ◽

Lewis Acid ◽

Cationic Polymerization ◽

Acid Catalyst ◽

Vinyl Ethers ◽

Controlled Polymerization ◽

Living Cationic Polymerization ◽

Lewis Acid Catalyst ◽

In Situ Generation

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