Living cationic polymerization of isobutyl vinyl ether by hydrogen iodide/Lewis acid initiating systems: effects of Lewis acid activators and polymerization kinetics

1989 ◽  
Vol 22 (4) ◽  
pp. 1552-1557 ◽  
Author(s):  
Kazushige Kojima ◽  
Mitsuo Sawamoto ◽  
Toshinobu Higashimura
Keyword(s):  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Polymerization Kinetics ◽  
Hydrogen Iodide ◽  
Living Cationic Polymerization

scholarly journals A well-defined block copolymer synthesis via living cationic polymerization and nitroxide-mediated polymerization using carboxylic acid-based alkoxyamines as a dual initiator

2016 ◽  
Vol 7 (8) ◽  
pp. 1659-1667 ◽  
Author(s):  
Dao Le ◽  
Trang N. T. Phan ◽  
Laurent Autissier ◽  
Laurence Charles ◽  
Didier Gigmes
Keyword(s):  
Carboxylic Acid ◽  
Block Copolymer ◽  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization ◽  
Nitroxide Mediated Polymerization ◽  
Protonic Acids

A series of carboxylic acid-based alkoxyamines associated with SnBr4, a Lewis acid, have been used as protonic acids of a binary initiating system to control the cationic polymerization of vinyl ether.

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