Living Radical Polymerization by Polyhedral Oligomeric Silsesquioxane-Holding Initiators:  Precision Synthesis of Tadpole-Shaped Organic/Inorganic Hybrid Polymers

2004 ◽  
Vol 37 (23) ◽  
pp. 8517-8522 ◽  
Author(s):  
Kohji Ohno ◽  
Satoshi Sugiyama ◽  
Kyoungmoo Koh ◽  
Yoshinobu Tsujii ◽  
Takeshi Fukuda ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Living Radical Polymerization ◽  
Hybrid Polymers ◽  
Inorganic Hybrid ◽  
Precision Synthesis ◽  
Oligomeric Silsesquioxane

Recent advances in organic–inorganic well-defined hybrid polymers using controlled living radical polymerization techniques

2016 ◽  
Vol 7 (24) ◽  
pp. 3950-3976 ◽  
Author(s):  
Zhenghe Zhang ◽  
Pengcheng Zhang ◽  
Yong Wang ◽  
Weian Zhang
Keyword(s):  
Silica Nanoparticles ◽  
Radical Polymerization ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Hybrid Polymers ◽  
Inorganic Hybrid ◽  
Recent Advances ◽  
Living Radical Polymerizations ◽  
Radical Polymerizations ◽  
Controlled Living Radical Polymerization

Controlled living radical polymerizations, such as ATRP and RAFT polymerization, could be utilized for the preparation of well-defined organic–inorganic hybrid polymers based on POSS, PDMS, silica nanoparticles, graphene, CNTs and fullerene.

scholarly journals Correction: Non-covalent polyhedral oligomeric silsesquioxane-polyoxometalates as inorganic–organic–inorganic hybrid materials for visible-light photocatalytic splitting of water

2018 ◽  
Vol 5 (10) ◽  
pp. 2678-2678 ◽  
Author(s):  
Rajendran Prabu ◽  
Karthik Peramaiah ◽  
Nallasamy Palanisami ◽  
Paolo P. Pescarmona ◽  
Bernaurdshaw Neppolian ◽  
...  
Keyword(s):  
Visible Light ◽  
Hybrid Materials ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Inorganic Hybrid ◽  
Oligomeric Silsesquioxane ◽  
Visible Light Photocatalytic

Correction for ‘Non-covalent polyhedral oligomeric silsesquioxane-polyoxometalates as inorganic–organic–inorganic hybrid materials for visible-light photocatalytic splitting of water’ by Rajendran Prabu et al., Inorg. Chem. Front., 2018, DOI: 10.1039/c8qi00449h.

Organic-Inorganic Hybrid Polymers from Atom Transfer Radical Polymerization and Poly(dimethylsiloxane)

2000 ◽  
pp. 270-283 ◽  
Author(s):  
Krzysztof Matyjaszewski ◽  
Peter J. Miller ◽  
Guido Kickelbick ◽  
Yoshiki Nakagawa ◽  
Steven Diamanti ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Hybrid Polymers ◽  
Inorganic Hybrid

A high-emissive and stable luminescent silafluorene hybrid constructed by hydrosilylation

2019 ◽  
Vol 43 (3-4) ◽  
pp. 144-148
Author(s):  
Ping Tang ◽  
Kai Xiang ◽  
Huijie Wei ◽  
Shuhong Li ◽  
Caihong Xu
Keyword(s):  
Thermal Stability ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Target Compound ◽  
Hybrid Molecule ◽  
Inorganic Hybrid ◽  
Hydrosilylation Reaction ◽  
Solid Fluorescence ◽  
Oligomeric Silsesquioxane ◽  
Nano Size ◽  
Thermal Stability Of

Under Karstedt’s catalyst, an organic–inorganic hybrid fluorescent nano-molecular dendrimer has been synthesized by grafting silafluorene units onto the polyhedral oligomeric silsesquioxane core through hydrosilylation reaction. The new hybrid molecule exhibits high solid fluorescence quantum efficiency because of the nano-size and large steric hindrance of the polyhedral oligomeric silsesquioxane core. Thermogravimetric analysis shows that the thermal stability of the target compound is effectively improved by the presence of polyhedral oligomeric silsesquioxane.

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