Recent advances in organic–inorganic well-defined hybrid polymers using controlled living radical polymerization techniques

2016 ◽  
Vol 7 (24) ◽  
pp. 3950-3976 ◽  
Author(s):  
Zhenghe Zhang ◽  
Pengcheng Zhang ◽  
Yong Wang ◽  
Weian Zhang
Keyword(s):  
Silica Nanoparticles ◽  
Radical Polymerization ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Hybrid Polymers ◽  
Inorganic Hybrid ◽  
Recent Advances ◽  
Living Radical Polymerizations ◽  
Radical Polymerizations ◽  
Controlled Living Radical Polymerization

Controlled living radical polymerizations, such as ATRP and RAFT polymerization, could be utilized for the preparation of well-defined organic–inorganic hybrid polymers based on POSS, PDMS, silica nanoparticles, graphene, CNTs and fullerene.

Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates

Synlett ◽  
2018 ◽  
Vol 29 (12) ◽  
pp. 1543-1551 ◽  
Author(s):  
Mao Chen ◽  
Honghong Gong ◽  
Yu Gu
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Atom Transfer ◽  
Reversible Addition ◽  
Controlled Living Radical Polymerization ◽  
Chain Transfer Polymerization ◽  
Semifluorinated Polymers

Fluorinated polymers are important materials for applications in many areas. This article summarizes the development of controlled/living radical polymerization (CRP) of semifluorinated (meth)acrylates, and briefly introduces their reaction mechanisms. While the classical CRP such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization and nitroxide-mediated radical polymerization (NMP) have promoted the preparation of semifluorinated polymers with tailor-designed architectures, recent development of photo-CRP has led to unprecedented accuracy and monomer scope. We expect that synthetic advances will facilitate the engineering of advanced fluorinated materials with unique properties.1 Introduction2 Atom Transfer Radical Polymerization3 Reversible Addition-Fragmentation Chain Transfer Polymerization4 Nitroxide-Mediated Radical Polymerization5 Photo-CRP Mediated with Metal Complexes6 Metal-free Photo-CRP7 Conclusion

Tailor-made gemcitabine prodrug nanoparticles from well-defined drug–polymer amphiphiles prepared by controlled living radical polymerization for cancer chemotherapy

2014 ◽  
Vol 2 (13) ◽  
pp. 1891-1901 ◽  
Author(s):  
Weiwei Wang ◽  
Chen Li ◽  
Ju Zhang ◽  
Anjie Dong ◽  
Deling Kong
Keyword(s):  
Radical Polymerization ◽  
Cancer Chemotherapy ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
High Drug ◽  
Polymer Conjugate ◽  
Anti Cancer ◽  
Controlled Living Radical Polymerization ◽  
Cancer Activity

Novel prodrug nanoparticles with a tailorable high drug payload and in vivo anti-cancer activity assembled from well-defined gemcitabine–polymer conjugate amphiphiles prepared by RAFT polymerization are presented.

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