Photoinduced Electron Transfer at the Core/Shell Interface of Polystyrene−Anthracene−Poly(methacrylic acid) Diblock Copolymer Micelles in Aqueous Media

1997 ◽  
Vol 101 (9) ◽  
pp. 1646-1656 ◽  
Author(s):  
A. R. Eckert ◽  
T. J. Martin ◽  
S. E. Webber
Keyword(s):  
Electron Transfer ◽  
Methacrylic Acid ◽  
Diblock Copolymer ◽  
Photoinduced Electron Transfer ◽  
Aqueous Media ◽  
Core Shell ◽  
The Core ◽  
Copolymer Micelles

scholarly journals Synthesis and Characterization of a Core-Shell Copolymer with Different Glass Transition Temperatures

Fibers ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 71
Author(s):  
Panagiotis Goulis ◽  
Ioannis A. Kartsonakis ◽  
Costas A. Charitidis
Keyword(s):  
Glass Transition ◽  
Methyl Methacrylate ◽  
Methacrylic Acid ◽  
Aqueous Media ◽  
Synthesis And Characterization ◽  
Core Shell ◽  
Experimental Procedure ◽  
The Core ◽  
Copolymer Poly

The aim of this study is to synthesize an organic core-shell co-polymer with a different glass transition temperature (Tg) between the core and the shell that can be used for several applications such as the selective debonding of coatings or the release of encapsulated materials. The co-polymer was synthesized using free radical polymerization and was characterized with respect to its morphology, composition and thermal behavior. The obtained results confirmed the successful synthesis of the co-polymer copolymer poly(methyl methacrylate)@poly(methacrylic acid-co-ethylene glycol dimethacrylate), PMMA@P(MAA-co-EGDMA), which can be used along with water-based solvents. Furthermore, the Tg of the polymer’s core PMMA was 104 °C, while the Tg of the shell P(MAA-co-EGDMA) was 228 °C, making it appropriate for a wide variety of applications. It is worth mentioning that by following this specific experimental procedure, methacrylic acid was copolymerized in water, as the shell of the copolymer, without forming a gel-like structure (hydrogel), as happens when a monomer is polymerized in aqueous media, such as in the case of super-absorbent polymers. Moreover, the addition and subsequent polymerization of the monomer methyl methacrylate (MAA) into the mixture of the already polymerized PMMA resulted in a material that was uniform in size, without any agglomerations or sediments.

Rational design of a boron-dipyrromethene-based fluorescent probe for detecting Pd2+ sensitively and selectively in aqueous media

The Analyst ◽  
2019 ◽  
Vol 144 (4) ◽  
pp. 1260-1264 ◽  
Author(s):  
Yannan Li ◽  
Li Yang ◽  
Mengqi Du ◽  
Guanjun Chang
Keyword(s):  
Electron Transfer ◽  
Fluorescent Probe ◽  
Photoinduced Electron Transfer ◽  
Rational Design ◽  
Aqueous Media ◽  
Transfer Mechanism ◽  
Electron Transfer Mechanism ◽  
Boron Dipyrromethene

A novel fluorescent probe for Pd2+ based on the BODIPY fluorophore exploiting the PET (Photoinduced Electron Transfer) mechanism was designed and successfully synthesized.

A water-soluble sulfonate-BODIPY based fluorescent probe for selective detection of HOCl/OCl−in aqueous media

The Analyst ◽  
2014 ◽  
Vol 139 (12) ◽  
pp. 2986-2989 ◽  
Author(s):  
Jiyoung Kim ◽  
Youngmi Kim
Keyword(s):  
Electron Transfer ◽  
Fluorescent Probe ◽  
Fluorescence Intensity ◽  
Photoinduced Electron Transfer ◽  
Aqueous Media ◽  
Water Soluble ◽  
Selective Detection ◽  
Buffer Solution ◽  
Aqueous Buffer ◽  
Aqueous Buffer Solution

A water-soluble sulfonate-BODIPY dye1was developed for the selective detection of HOCl/OCl−in aqueous buffer solution. The probe, which displays extremely weak fluorescence owing to efficient photoinduced electron transfer (PeT) from the pendant catechol donor, responds to HOCl/OCl−through a dramatic enhancement of its fluorescence intensity.

Photoinduced electron transfer of nanohybrids of carbon nanohorns with amino groups and tetrabenzoic acid porphyrin in aqueous media

2009 ◽  
Vol 33 (11) ◽  
pp. 2261 ◽  
Author(s):  
Atula S. D. Sandanayaka ◽  
Osamu Ito ◽  
Takatsugu Tanaka ◽  
Hiroyuki Isobe ◽  
Eiichi Nakamura ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Aqueous Media ◽  
Amino Groups ◽  
Carbon Nanohorns

A highly selective colorimetric Cys sensor based on core-substituted naphthalene diimides

RSC Advances ◽  
2015 ◽  
Vol 5 (122) ◽  
pp. 100697-100701 ◽  
Author(s):  
Sharad R. Bobe ◽  
Rajesh S. Bhosale ◽  
Santosh P. Goskulwad ◽  
Avinash L. Puyad ◽  
Sheshanath V. Bhosale ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Selective Detection ◽  
The Core ◽  
Naphthalene Diimides

This study presents the core-substituted naphthalenediimide based probe 1 for the selective detection of cysteine via photoinduced electron transfer (PET) effect.

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