Spectroscopic Characterization of Inorganic Host:Organic Dopant Films Fabricated via Laser-Assisted Molecular Beam Deposition

1996 ◽  
Vol 100 (25) ◽  
pp. 10707-10709 ◽  
Author(s):  
R. L. DeLeon ◽  
W. M. K. P. Wijekoon ◽  
U. Narang ◽  
M. L. Hall ◽  
P. N. Prasad ◽  
...  
2017 ◽  
Vol 8 ◽  
pp. 1191-1204 ◽  
Author(s):  
Rasha K Al-Shewiki ◽  
Carola Mende ◽  
Roy Buschbeck ◽  
Pablo F Siles ◽  
Oliver G Schmidt ◽  
...  

Subsequent treatment of H2TPP(CO2H)4 (tetra(p-carboxylic acid phenyl)porphyrin, 1) with an excess of oxalyl chloride and HNR2 afforded H2TPP(C(O)NR2)4 (R = Me, 2; iPr, 3) with yields exceeding 80%. The porphyrins 2 and 3 could be converted to the corresponding metalloporphyrins MTPP(C(O)NR2)4 (R = Me/iPr for M = Zn (2a, 3a); Cu (2b, 3b); Ni (2c, 3c); Co (2d, 3d)) by the addition of 3 equiv of anhydrous MCl2 (M = Zn, Cu, Ni, Co) to dimethylformamide solutions of 2 and 3 at elevated temperatures. Metalloporphyrins 2a–d and 3a–d were obtained in yields exceeding 60% and have been, as well as 2 and 3, characterized by elemental analysis, electrospray ionization mass spectrometry (ESIMS) and IR and UV–vis spectroscopy. Porphyrins 2, 2a–d and 3, 3a–d are not suitable for organic molecular beam deposition (OMBD), which is attributed to their comparatively low thermal stability as determined by thermogravimetric analysis (TG) of selected representatives.


1994 ◽  
Vol 359 ◽  
Author(s):  
Kiyoshi Yase ◽  
Takuya Saraya ◽  
Kazuhiro Kudo

ABSTRACTFullerene C60 thin solid films have been fabricated on the (001) surfaces of alkali halides (NaCl, KCI and KBr) and muscovite by organic molecular beam deposition (OMBD) technique. Pure C60 powder was sublimated from the precisely temperature-controlled K-cell at low pressure (10−7 Torr) and deposited onto the substrates kept in the range 125 –300 °C. Increasing both the temperature of K-cell and the substrate temperature, fine crystals grow with different size, shape and distance between neighbors. The dependence of the size and density of island crystals on the deposition conditions revealed the mechanism of crystal growth and the effect of interaction between molecules and substrate surface.


1998 ◽  
Vol 130-132 ◽  
pp. 651-657 ◽  
Author(s):  
Yuji Yoshida ◽  
Hiroshi Takiguchi ◽  
Takeshi Hanada ◽  
Nobutaka Tanigaki ◽  
Eun Mi Han ◽  
...  

2004 ◽  
Vol 464-465 ◽  
pp. 398-402 ◽  
Author(s):  
Hirotomo Yanagisawa ◽  
Tsuyoshi Tamaki ◽  
Masakazu Nakamura ◽  
Kazuhiro Kudo

2011 ◽  
Vol 99 (18) ◽  
pp. 182103 ◽  
Author(s):  
Shu Yang ◽  
Sen Huang ◽  
Hongwei Chen ◽  
Michael Schnee ◽  
Qing-Tai Zhao ◽  
...  

1995 ◽  
Vol 34 (Part 1, No. 7B) ◽  
pp. 3852-3857 ◽  
Author(s):  
Hiroyuki Fuchigami ◽  
Sachiko Tanimura ◽  
Yasushi Uehara ◽  
Tetsuyuki Kurata ◽  
Sei Tsunoda

1999 ◽  
Vol 12 (2-3) ◽  
pp. 301-305 ◽  
Author(s):  
C Botta ◽  
S Destri ◽  
W Porzio ◽  
A Sassella ◽  
A Borghesi ◽  
...  

1996 ◽  
Vol 426 ◽  
Author(s):  
H. Y. Ueng ◽  
D. Y. Chang ◽  
J. L. Lin

AbstractCuInSe2 thin films grown on Corning 7059 glass substrates were prepared by molecular beam deposition method with various Cu/In ratios in order to study the relationship between composition and material properties. Under a fixed copper beam flux intensity and overpressure selenium environments, the composition of films was modulated by changing the indium beam flux: intensity to obtain Cu-rich or In-rich films. The X-ray diffraction patterns show that the epitaxy films grown onto glass substrates are the polycrystalline structure. The grain size of polycrystalline films indicate that the surface morphology of the films are varied as a function of Cu/In ratio.


2001 ◽  
Vol 2 (3-4) ◽  
pp. 143-154 ◽  
Author(s):  
Jiangeng Xue ◽  
Jingui Qin ◽  
Peter V. Bedworth ◽  
Karen Kustedjo ◽  
Seth R. Marder ◽  
...  

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