Photoluminescence Quenching of CdSe Core/Shell Quantum Dots by Hole Transporting Materials

2009 ◽  
Vol 113 (5) ◽  
pp. 1886-1890 ◽  
Author(s):  
Youlin Zhang ◽  
Pengtao Jing ◽  
Qinghui Zeng ◽  
Yajuan Sun ◽  
Huaipeng Su ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Core Shell ◽  
Cdse Core ◽  
Photoluminescence Quenching ◽  
Hole Transporting ◽  
Hole Transporting Materials

scholarly journals Investigation on photoluminescence quenching of CdSe/ZnS quantum dots by organic charge transporting materials

2015 ◽  
Vol 33 (4) ◽  
pp. 709-713 ◽  
Author(s):  
Qu Yuqiu ◽  
Zhang Liuyang ◽  
An Limin ◽  
Wei Hong
Keyword(s):  
Quantum Dots ◽  
Oxidation Potential ◽  
Core Shell ◽  
Photoluminescence Intensity ◽  
Dynamic Quenching ◽  
Photoluminescence Quenching ◽  
Time Resolved ◽  
Quenching Efficiency ◽  
Hole Transporting ◽  
Time Resolved Photoluminescence

AbstractThe effect of different organic charge transporting materials on the photoluminescence of CdSe/ZnS core/shell quantum dots has been studied by means of steady-state and time-resolved photoluminescence spectroscopy. With an increase in concentration of the organic charge transporting material in the quantum dots solutions, the photoluminescence intensity of CdSe/ZnS quantum dots was quenched greatly and the fluorescence lifetime was shortened gradually. The quenching efficiency of CdSe/ZnS core/shell quantum dots decreased with increasing the oxidation potential of organic charge transporting materials. Based on the analysis, two pathways in the photoluminescence quenching process have been defined: static quenching and dynamic quenching. The dynamic quenching is correlated with hole transporting from quantum dots to the charge transporting materials.

Study on Photoluminescence Quenching of CdSe Core/Shell Quantum Dots with Organic Charge Transferring Material

2014 ◽  
Vol 981 ◽  
pp. 883-886
Author(s):  
Yu Qiu Qu ◽  
Liu Yang Zhang ◽  
Li Min An ◽  
Hong Wei ◽  
Gui Fan Li
Keyword(s):  
Quantum Dots ◽  
Fluorescence Quenching ◽  
Fluorescence Lifetime ◽  
Spectral Methods ◽  
Shell Structure ◽  
Core Shell ◽  
Cdse Core ◽  
Photoluminescence Quenching ◽  
Molecular Concentration ◽  
Pl Quenching

The effect of organic charge transferring material (CTM) on fluorescence of CdSe/ZnS and CdSe/CdS/ZnS core/shell quantum dots (QDs) are investigated by spectral methods. With the increase of organic molecular concentration, CTM can greatly quench the fluorescence of QDs and shorten the fluorescence lifetime of QDs. In the process of interacting with CTM, the efficiency of fluorescence quenching for CdSe/ZnS is significantly higher than that for CdSe/CdS/ZnS. The results of experiment show that the shell structure of QDs plays the major role in photoluminescence (PL) quenching. The mechanism of PL quenching of QDs is also analyzed.

Resistive Switching in CdTe/CdSe Core–Shell Quantum Dots Embedded Chitosan-Based Memory Devices

2021 ◽  
Author(s):  
Zolile Wiseman Dlamini ◽  
Sreedevi Vallabhapurapu ◽  
Olamide Abiodun Daramola ◽  
Potlaki Foster Tseki ◽  
Rui Werner Macedo Krause ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Resistive Switching ◽  
Core Shell ◽  
Cdse Core ◽  
Active Layers ◽  
Ag Electrodes ◽  
Exponential Decrease ◽  
Conductive Bridge ◽  
Bipolar Memory ◽  
State Resistance

In this paper, we report on the resistive switching (RS) and conduction mechanisms in devices consisting of CdTe/CdSe core–shell quantum dots embedded chitosan composites active layer. Two devices with active layers sandwiched between (1) Al and Ag, and (2) ITO and Ag electrodes were studied. Both devices exhibited bipolar memory behavior with [Formula: see text] V and [Formula: see text][Formula: see text]V, for the Al-based device, while [Formula: see text] V and [Formula: see text][Formula: see text]V were observed for the ITO-based device, enabling both devices to be operated at low powers. However, the switching mechanisms of both devices were different, i.e., RS in Al device was attributed to conductive bridge mechanism, while space-charge-limited driven conduction filament attributed the switching mechanism of the ITO device. Additionally, the Al-based device showed long retention ([Formula: see text][Formula: see text]s) and a reasonable large ([Formula: see text]) ON/OFF ratio. Additionally, for this device, we also observed sweeping cycle-induced reversal of voltage polarity of the [Formula: see text] and [Formula: see text]. In contrast, we observed that increasing sweeping cycles resulted in an exponential decrease of the OFF-state resistance of the ITO-based device.

Photoluminescence properties of CdTe∕CdSe core-shell type-II quantum dots

2006 ◽  
Vol 99 (12) ◽  
pp. 123521 ◽  
Author(s):  
C. H. Wang ◽  
T. T. Chen ◽  
K. W. Tan ◽  
Y. F. Chen ◽  
C. T. Cheng ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Core Shell ◽  
Type Ii ◽  
Photoluminescence Properties ◽  
Cdse Core ◽  
Shell Type

Micro-Photoluminescence Study of Bio-conjugated CdSe/ZnS Nanocrystals

2013 ◽  
Vol 1617 ◽  
pp. 157-162
Author(s):  
L. Borkovska ◽  
N. Korsunska ◽  
T. Stara ◽  
O. Kolomys ◽  
V. Strelchuk ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Thermal Annealing ◽  
Interleukin 10 ◽  
Half Width ◽  
Core Shell ◽  
Cdse Core ◽  
Photoluminescence Study ◽  
Pl Spectra ◽  
Band Position ◽  
Zns Nanocrystals

ABSTRACTThe effect of bio-conjugation of CdSe/ZnS core-shell quantum dots (QDs) with Interleukin 10 (IL-10) antibodies on the aging of photoluminescence (PL) spectra of the QDs was investigated. The aging occurred upon storage of QDs for about 2 years or thermal annealing at 190 oC for up to 12 hours at atmospheric ambience and consisted in “blue” shifting the PL band position, increasing a PL band half-width and decreasing the PL intensity. The bio-conjugation is found to promote PL aging. The aging upon storage is attributed to the oxidation that decreases the QD core dimension, while the aging upon thermal annealing can be due to both oxidation and alloying of CdSe core and ZnS shell.

Photoluminescence transformation of core/shell CdSe/ZnS quantum dots at the conjugation to biomolecules

2012 ◽  
Vol 1376 ◽  
Author(s):  
T. V. Torchynska ◽  
I. Ch. Ballardo Rodríguez ◽  
Ye. Shcherbyna
Keyword(s):  
Quantum Dots ◽  
High Energy ◽  
Core Shell ◽  
Polymer Interfaces ◽  
Cdse Core ◽  
Exciton Emission ◽  
Pl Spectra ◽  
Pl Spectrum ◽  
The Comparative Study ◽  
Color Emission

AbstractThe paper presents the results of PL spectrum analysis of CdSe/ZnS QDs covered by PEG polymer with and without bioconjugation to bio-molecules .– the Osteopontin antibodies. Commercial CdSe/ZnS QDs used in the study are characterized by the color emission with the maximum at 640 nm (1.96 eV) at 300K. It is shown that PL spectra of nonconjugated QDs can be presented as a superposition of PL bands related to exciton emission in the CdSe core (1.96 eV) and some high energy PL bands (in the spectral range 2.37 .– 3.00 eV). The comparative study of PL spectrum at high (300K) and low (10K) temperatures has testified that high energy PL bands deal with electronhole emission via interface states at the CdSe/ZnS/polymer interfaces.It is revealed that the QD bioconjugation to the anti Osteopontin antibody is accompanied by the change dramatically in PL spectra. Main features of PL spectrum transformstions deal with decreasing the PL intensity of interface related PL bands and the rise of intensity of CdSe core related PL bands. The explanation of mentioned effects has been proposed on the base of re-charging of interface related states at the bioconjugation process.

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