Concerning the Ground State and S1 and T1 Photoexcited States of the Homoleptic Quadruply Bonded Complexes Mo2(O2CC6H4-p-X)4, where X = C≡C–H or C≡N

Samantha E. Brown-Xu; Malcolm H. Chisholm; Christopher B. Durr; Thomas F. Spilker

doi:10.1021/jp408667m

Concerning the Ground State and S1 and T1 Photoexcited States of the Homoleptic Quadruply Bonded Complexes Mo2(O2CC6H4-p-X)4, where X = C≡C–H or C≡N

The Journal of Physical Chemistry A ◽

10.1021/jp408667m ◽

2013 ◽

Vol 117 (50) ◽

pp. 13893-13898 ◽

Cited By ~ 7

Author(s):

Samantha E. Brown-Xu ◽

Malcolm H. Chisholm ◽

Christopher B. Durr ◽

Thomas F. Spilker

Keyword(s):

Ground State ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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MM quadruply bonded complexes supported by vinylbenzoate ligands: synthesis, characterization, photophysical properties and application as synthons

Chemical Science ◽

10.1039/c4sc02542c ◽

2015 ◽

Vol 6 (3) ◽

pp. 1780-1791 ◽

Cited By ~ 4

Author(s):

Samantha E. Brown-Xu ◽

Malcolm H. Chisholm ◽

Christopher B. Durr ◽

Thomas F. Spilker ◽

Philip J. Young

Keyword(s):

Photophysical Properties ◽

Higher Order ◽

Coupling Reactions ◽

Heck Coupling ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

MM complexes as potential synthons for the development of higher order extended structures via Heck coupling reactions, exhibiting interesting photophysical properties.

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Electronically Coupled MM Quadruply-Bonded Complexes (M = Mo or W) Employing Functionalized Terephthalate Bridges: Toward Molecular Rheostats and Switches

Journal of the American Chemical Society ◽

10.1021/ja0550982 ◽

2005 ◽

Vol 127 (51) ◽

pp. 18150-18158 ◽

Cited By ~ 32

Author(s):

Malcolm H. Chisholm ◽

Florian Feil ◽

Christopher M. Hadad ◽

Nathan J. Patmore

Keyword(s):

Bonded Complexes ◽

Quadruply Bonded Complexes

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Photophysical Properties of MM Quadruply Bonded Complexes Supported by Carboxylate Ligands, MM = Mo2, MoW, or W2

Accounts of Chemical Research ◽

10.1021/ar3002206 ◽

2012 ◽

Vol 46 (2) ◽

pp. 529-538 ◽

Cited By ~ 30

Author(s):

Malcolm H. Chisholm ◽

Terry L. Gustafson ◽

Claudia Turro

Keyword(s):

Photophysical Properties ◽

Carboxylate Ligands ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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The Physical and Electronic Structure of M2 Quadruply Bonded Complexes: A Density Functional Theory Study

Journal of Cluster Science ◽

10.1007/s10876-006-0074-9 ◽

2006 ◽

Vol 18 (1) ◽

pp. 27-49 ◽

Cited By ~ 10

Author(s):

Malcolm H. Chisholm ◽

Jason S. D’Acchioli ◽

Christopher M. Hadad

Keyword(s):

Density Functional Theory ◽

Electronic Structure ◽

Density Functional ◽

Density Functional Theory Study ◽

Functional Theory ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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Photophysical Studies of Metal to Ligand Charge Transfer Involving Quadruply Bonded Complexes of Molybdenum and Tungsten

Accounts of Chemical Research ◽

10.1021/ar500256f ◽

2015 ◽

Vol 48 (3) ◽

pp. 877-885 ◽

Cited By ~ 20

Author(s):

Malcolm H. Chisholm ◽

Samantha E. Brown-Xu ◽

Thomas F. Spilker

Keyword(s):

Charge Transfer ◽

Ligand Charge Transfer ◽

Photophysical Studies ◽

And Tungsten ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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Photophysical Properties of cis-Mo2 Quadruply Bonded Complexes and Observation of Photoinduced Electron Transfer to Titanium Dioxide

Journal of the American Chemical Society ◽

10.1021/ja504944d ◽

2014 ◽

Vol 136 (32) ◽

pp. 11428-11435 ◽

Cited By ~ 9

Author(s):

Samantha E. Brown-Xu ◽

Malcolm H. Chisholm ◽

Christopher B. Durr ◽

Terry L. Gustafson ◽

Thomas F. Spilker

Keyword(s):

Electron Transfer ◽

Titanium Dioxide ◽

Photoinduced Electron Transfer ◽

Photophysical Properties ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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Electron delocalization in the S1 and T1 metal-to-ligand charge transfer states of trans-substituted metal quadruply bonded complexes

Proceedings of the National Academy of Sciences ◽

10.1073/pnas.1103082108 ◽

2011 ◽

Vol 108 (20) ◽

pp. 8152-8156 ◽

Cited By ~ 44

Author(s):

B. G. Alberding ◽

M. H. Chisholm ◽

J. C. Gallucci ◽

Y. Ghosh ◽

T. L. Gustafson

Keyword(s):

Charge Transfer ◽

Electron Delocalization ◽

Ligand Charge Transfer ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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Spectroscopy and structure of quadruply bonded complexes under extreme pressure (Re2X82-, Mo2Cl4(PMe3)4)

Inorganic Chemistry ◽

10.1021/ic00343a033 ◽

1990 ◽

Vol 29 (18) ◽

pp. 3447-3452 ◽

Cited By ~ 7

Author(s):

David E. Morris ◽

C. Drew Tait ◽

R. Brian Dyer ◽

Jon R. Schoonover ◽

Michael D. Hopkins ◽

...

Keyword(s):

Extreme Pressure ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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Synthesis and characterization of trans-M2(TiPB)2(O2C-CHCH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(TiPB)2L2, where TiPB = 2,4,6-triisopropylbenzoate and L = π-accepting carboxylate ligand

Dalton Transactions ◽

10.1039/c1dt10788g ◽

2011 ◽

Vol 40 (40) ◽

pp. 10658 ◽

Cited By ~ 14

Author(s):

Brian G. Alberding ◽

Malcolm H. Chisholm ◽

Benjamin J. Lear ◽

Vesal Naseri ◽

Carly R. Reed

Keyword(s):

Charge Transfer ◽

Carboxylate Ligand ◽

Synthesis And Characterization ◽

Ligand Charge Transfer ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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High-pressure spectroscopic studies of dihalotetrakis(pivalato)dirhenium(III) metal-metal quadruply bonded complexes

Inorganic Chemistry ◽

10.1021/ic00294a006 ◽

1988 ◽

Vol 27 (21) ◽

pp. 3701-3706 ◽

Cited By ~ 6

Author(s):

R. T. Roginski ◽

T. L. Carroll ◽

A. Moroz ◽

B. R. Whittlesey ◽

J. R. Shapley ◽

...

Keyword(s):

High Pressure ◽

Spectroscopic Studies ◽

Metal Metal ◽

Bonded Complexes ◽

Quadruply Bonded Complexes

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