High-pressure spectroscopic studies of dihalotetrakis(pivalato)dirhenium(III) metal-metal quadruply bonded complexes

1988 ◽  
Vol 27 (21) ◽  
pp. 3701-3706 ◽  
Author(s):  
R. T. Roginski ◽  
T. L. Carroll ◽  
A. Moroz ◽  
B. R. Whittlesey ◽  
J. R. Shapley ◽  
...  
Keyword(s):  
High Pressure ◽  
Spectroscopic Studies ◽  
Metal Metal ◽  
Bonded Complexes ◽  
Quadruply Bonded Complexes

ChemInform Abstract: High-Pressure Spectroscopic Studies of Dihalotetrakis(pivalato)dirhenium(III) Metal-Metal Quadruply Bonded Complexes.

ChemInform ◽  
1989 ◽  
Vol 20 (6) ◽  
Author(s):  
R. T. ROGINSKI ◽  
T. L. CARROLL ◽  
A. MOROZ ◽  
B. R. WHITTLESEY ◽  
J. R. SHAPLEY ◽  
...  
Keyword(s):  
High Pressure ◽  
Spectroscopic Studies ◽  
Metal Metal ◽  
Bonded Complexes ◽  
Quadruply Bonded Complexes

In-situ infrared spectroscopic studies of hydroxyl in amphiboles at high pressure

2016 ◽  
Vol 101 (3) ◽  
pp. 706-712 ◽  
Author(s):  
Elizabeth C. Thompson ◽  
Andrew J. Campbell ◽  
Zhenxian Liu
Keyword(s):  
High Pressure ◽  
Spectroscopic Studies ◽  
Infrared Spectroscopic

The gas phase reactivity of the dimethylchloronium ion with alkylbenzenes

1981 ◽  
Vol 59 (15) ◽  
pp. 2412-2416 ◽  
Author(s):  
John A. Stone ◽  
Margaret S. Lin ◽  
Jeffrey Varah
Keyword(s):  
High Pressure ◽  
Gas Phase ◽  
Mass Spectrometer ◽  
Aromatic Hydrocarbons ◽  
Relative Rate ◽  
Ion Source ◽  
Nucleophilic Displacement ◽  
Rate Of Reaction ◽  
Displacement Reactions ◽  
Bonded Complexes

The reactivity of the dimethylchloronium ion with a series of aromatic hydrocarbons has been studied in a high pressure mass spectrometer ion source using the technique of reactant ion monitoring. Benzene is unreactive but all others, from toluene to mesitylene, react by CH3+ transfer to yield σ-bonded complexes. The relative rate of reaction increases with increasing exothermicity in line with current theories of nucleophilic displacement reactions.

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